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e form of alkaline chlorides it is found in sea-water and various spring waters, and in the tissues of animals and plants; while, as hydrochloric acid it is found in volcanic gases. The preparation of chlorine, both on the small scale and commercially, depends on the oxidation of hydrochloric acid; the usual oxidizing agent is manganese dioxide, which, when heated with concentrated hydrochloric acid, forms manganese chloride, water and chlorine:--MnO2 + 4HCl = MnCl2 + 2H2O + Cl2. The manganese dioxide may be replaced by various other substances, such as red lead, lead dioxide, potassium bichromate, and potassium permanganate. Instead of heating hydrochloric acid with manganese dioxide, use is frequently made of a mixture of common salt and manganese dioxide, to which concentrated sulphuric acid is added and the mixture is then heated:--MnO2 + 2NaCl + 3H2SO4 = MnSO4 + 2NaHSO4 + 2H2O + Cl2. Chlorine may also be obtained by the action of dilute sulphuric acid on bleaching powder. Owing to the enormous quantities of chlorine required for various industrial purposes, many processes have been devised, either for the recovery of the manganese from the crude manganese chloride of the chlorine stills, so that it can be again utilized, or for the purpose of preparing chlorine without the necessity of using manganese in any form (see ALKALI MANUFACTURE). Owing to the reduction in the supply of available hydrochloric acid (on account of the increasing use of the "ammonia-soda" process in place of the "Leblanc" process for the manufacture of soda) Weldon tried to adapt the former to the production of chlorine or hydrochloric acid. His method consisted in using magnesia instead of lime for the recovery of the ammonia (which occurs in the form of ammonium chloride in the ammonia-soda process), and then by evaporating the magnesium chloride solution and heating the residue in steam, to condense the acid vapours and so obtain hydrochloric acid. One day before him E. Solvay had patented the same process, but neither of them was able to make the method a commercial success. However, in conjunction with Pechiney, of Salindres (near Alais, France), the Weldon-Pechiney process was worked out. The residual magnesium chloride of the ammonia-soda process is evaporated until it ceases to give off hydrochloric acid, and is then mixed with more magnesia: the magnesium oxychloride formed is broken into small pi
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