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ferrous sulphate have all been used as chlorine carriers. The atomic weight of chlorine was determined by J. Berzelius and by F. Penny (_Phil, Trans._, 1839, 13). J.S. Stas, from the synthesis of silver chloride, obtained the value 35.457 (O = 16), and C. Marignac found the value 34.462. More recent determinations are: H.B. Dixon and E.C. Edgar (_Phil. Trans._, 1905); T.W. Richards and G. Jones (_Abst. J.C.S._, 1907); W.A. Noyes and H.C. Weber (ibid., 1908), and Edgar (ibid., 1908). _Hydrochloric Acid._--Chlorine combines with hydrogen to form hydrochloric acid, HCl, the only known compound of these two elements. The acid itself was first obtained by J.R. Glauber in about 1648, but J. Priestley in 1772 was the first to isolate it in the gaseous condition, and Sir H. Davy in 1810 showed that it contained hydrogen and chlorine only, as up to that time it was considered to contain oxygen. It may be prepared by the direct union of its constituents (see Burgess and Chapman, _J.C.S._, 1906, 89, p. 1399), but on the large scale and also for the preparation of small quantities it is made by the decomposition of salt by means of concentrated sulphuric acid, NaCl+H2SO4=NaHSO4+HCl. It is chiefly obtained as a by-product in the manufacture of soda-ash by the Leblanc process (see ALKALI MANUFACTURE). The commercial acid is usually yellow in colour and contains many impurities, such as traces of arsenic, sulphuric acid, chlorine, ferric chloride and sulphurous acid; but these do not interfere with its application to the preparation of bleaching powder, in which it is chiefly consumed. Without further purification it is also used for "souring" in bleaching, and in tin and lead soldering. It is a colourless gas, which can be condensed by cold and pressure to a liquid boiling at -83.7 deg. C., and can also be solidified, the solid melting at -112.5 deg. C. (K. Olszewski). Its critical temperature is 52.3 deg. C., and its critical pressure is 86 atmos. The gas fumes strongly in moist air, and it is rapidly dissolved by water, one volume of water at 0 deg. C. absorbing 503 volumes of the gas. The gas does not obey Henry's law, that is, its solubility in water is not proportional to its pressure. It is one of the "strong" acids, being ionized to the extent of about 91.4% in decinormal solution. The strongest aqueous solution of hydrochloric acid at 15 deg. C. contains 42.9% of the acid, and has
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