FREE BOOKS

Author's List




PREV.   NEXT  
|<   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108  
109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   >>   >|  
ly used in connection with circuits that are continuously closed, they are called _closed-circuit cells_. The other cells, which are better adapted for intermittent current, are commonly used on circuits which stand open most of the time and are closed only occasionally when their current is desired. For this reason these are termed _open-circuit cells_. _Open-Circuit Cells_. LeClanche Cell:--By far the most important primary cell for telephone work is the so-called LeClanche cell. This assumes a large variety of forms, but always employs zinc as the negatively charged element, carbon as the positively charged element, and a solution of sal ammoniac as the electrolyte. This cell employs a chemical method of taking care of polarization, the depolarizing agent being peroxide of manganese, which is closely associated with the carbon element. The original form of the LeClanche cell, a form in which it was very largely used up to within a short time ago, is shown in Fig. 61. In this the carbon element is placed within a cylindrical jar of porous clay, the walls of this jar being of such consistency as to allow moisture slowly to permeate through it. Within this porous cup, as it is called, a plate or disk of carbon is placed, and around this the depolarizing agent, consisting of black oxide of manganese. This is usually mixed with, broken carbon, so as to increase the effective area of the carbon element in contact with the depolarizing agent, and also to reduce the total internal resistance of the cell. The zinc electrode usually consisted merely in a rod of zinc, as shown, with a suitable terminal at its upper end. [Illustration: Fig. 61. LeClanche Cell] The chemical action taking place within the LeClanche cell is, briefly, as follows: Sal ammoniac is chemically known as chloride of ammonium and is a combination of chlorine and ammonia. In the action which is assumed to accompany the passage of current in this cell, the sal ammoniac is decomposed, the chlorine leaving the ammonia to unite with an atom of the zinc plate, forming chloride of zinc and setting free ammonia and hydrogen. The ammonia is immediately dissolved in the water of the cell, and the hydrogen enters the porous cup and would speedily polarize the cell by adhering to the carbon plate but for the fact that it encounters the peroxide of manganese. This material is exceedingly rich in oxygen and it therefore readily gives up a part of its oxygen, wh
PREV.   NEXT  
|<   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108  
109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   >>   >|  



Top keywords:

carbon

 

LeClanche

 

element

 
ammonia
 

manganese

 

depolarizing

 

ammoniac

 
called
 

closed

 

current


porous

 

chemical

 
employs
 

taking

 

charged

 
action
 

chloride

 

chlorine

 

oxygen

 

hydrogen


peroxide
 

circuits

 
circuit
 

briefly

 

Illustration

 

ammonium

 

adapted

 

chemically

 
intermittent
 

internal


resistance
 

reduce

 

contact

 

electrode

 
consisted
 

combination

 

terminal

 

suitable

 
assumed
 

encounters


material

 

adhering

 

speedily

 

polarize

 
exceedingly
 

readily

 

continuously

 

enters

 
leaving
 

decomposed