FREE BOOKS

Author's List




PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115  
116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   >>   >|  
trouble has been experienced in gravity cells due to the creeping of the salts over the edge of the jar. Frequently the upper edges of the jars are coated by dipping in hot paraffin wax in the hope of preventing this. Sometimes oil is poured on top of the fluid in the jar to prevent the creeping of the salts and the evaporation of the electrolyte. The following account of experiments performed by Mr. William Reid, of Chicago, throws light on the relative advantages of these and other methods of preventing creeping. The experiment was made with gravity cells having 5-inch by 7-inch glass jars. Four cells were made up and operated in a rather dry, warm place, although perhaps under no more severe local conditions than would be found in most telephone exchanges. Cell No. 1 was a plain cell as ordinarily used. Cell No. 2 had the top of the rim of the jar treated with paraffin wax by dipping the rim to about one inch in depth in melted paraffin wax. Cell No. 3 had melted paraffin wax poured over the surface of the liquid forming a seal about 3/16 inch in thickness. After cooling, a few small holes were bored through the seal to let gases escape. Cell No. 4 had a layer of heavy paraffin oil nearly 1/2 inch in thickness (about 6 oz. being used) on top of the solutions. These cells were all run on a load of .22 to .29 amperes for 15-1/2 hours per day for thirty days, after which the following results were noted: (_a_) The plain cell, or cell No. 1, had to have 26 ounces of water added to it to replace that which had evaporated. The creeping of zinc sulphate salts was very bad. (_b_) The waxed rim cell, or cell No. 2, evaporated 26 ounces of water and the creeping of zinc sulphate salts was not prevented by the waxed rim. The wax proved of no value. (_c_) The wax sealed cell, or cell No. 3, showed practically no evaporation and only very slight creeping of zinc sulphate salts. The creeping of salts that took place was only around spots where the edges of the seal were loose from the jar. (_d_) The paraffin oil sealed cell, or cell No. 4, showed no evaporation and no creeping of salts. It was concluded by Mr. Reid from the above experiments that the wax applied to the rim of the jar is totally ineffective and has no merits. The wax seal loosens around the edges and does not t
PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115  
116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   >>   >|  



Top keywords:

creeping

 

paraffin

 
evaporation
 

sulphate

 

sealed

 

showed

 

gravity

 
melted
 

dipping

 

preventing


evaporated

 

experiments

 

ounces

 
thickness
 
poured
 

thirty

 

solutions

 
amperes
 

loosens

 

practically


slight
 

ineffective

 
merits
 

totally

 

applied

 

concluded

 

results

 

replace

 

prevented

 
proved

escape

 

liquid

 

methods

 
experiment
 

operated

 
prevent
 
coated
 

electrolyte

 

Sometimes

 
trouble

account

 
relative
 
advantages
 

throws

 

Chicago

 

performed

 

William

 
Frequently
 
forming
 

surface