FREE BOOKS

Author's List




PREV.   NEXT  
|<   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33   34   35  
36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   >>   >|  
e lignocelluloses. The actual production of furfural by boiling with condensing acids is a quantitative measure of only a portion, i.e. certain members of the group. The hydroxyfurfurals, not being volatile, are not measured in this way. By secondary reactions they may yield some furfural, but as they are highly reactive compounds, and most readily condensed, they are for the most part converted into complex 'tarry' products. Hence we have no means, as yet, of estimating those tissue constituents which yield hydroxyfurfurals; also we have no measure of the furfurane-rings existing performed in such a condensed complex as lignone. But, chemists having added in the last few years a large number of facts and well-defined probabilities, it is clear that the further investigation of the furfuroid group will take its stand upon a much more adequate basis than heretofore. On the view of 'furfural-yielding' being co-extensive with 'pentose or pentosane,' not only were a number of important facts obscured or misinterpreted, but there was a barrenness of suggestion of genetic relationships. As the group has been widened very much beyond these limits, it is clear that if any group term or designation is to be retained that of 'furfuroid' is 'neutral' in character, and equally applicable to saturated substances of such widely divergent chemical character as pentoses, hexosones, glycuronic acid, and perhaps, most important of all, levulose itself, all of which are susceptible of condensation to furfural or furfurane derivatives, as well as to those unsaturated compounds, constituents of plant tissues which are already furfurane derivatives. From the chemical point of view such terms are perhaps superfluous. But physiological relationships have a significance of their own; and there is a physiological or functional cohesion marking this group which calls for recognition, at least for the time, and we therefore propose to retain the term furfuroid.[1] ~General Experimental Methods.~--In the investigation of the cellulose group it is clear that methods of ultimate hydrolysis are of first importance. None are so convenient as those which are based on the action of sulphuric acid, more or less concentrated (H_{2}SO_{4}.3H_{2}O - H_{2}SO_{4}H_{2}O). Such methods have been frequently employed in the investigations noted in this volume. We notice a common deficiency in the interpretation of the results. It appears to be sufficient to
PREV.   NEXT  
|<   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33   34   35  
36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   >>   >|  



Top keywords:

furfural

 

furfuroid

 

furfurane

 

investigation

 

physiological

 
constituents
 

character

 

methods

 

important

 

chemical


derivatives
 

relationships

 

number

 

hydroxyfurfurals

 

complex

 

compounds

 

measure

 
condensed
 

unsaturated

 

sufficient


superfluous

 

concentrated

 

significance

 

volume

 

tissues

 

substances

 
widely
 
saturated
 

frequently

 
equally

applicable

 

divergent

 

pentoses

 
susceptible
 

investigations

 

levulose

 

hexosones

 

glycuronic

 
condensation
 

functional


cellulose

 

action

 

interpretation

 

Experimental

 

sulphuric

 

Methods

 
ultimate
 
convenient
 

common

 

notice