FREE BOOKS

Author's List




PREV.   NEXT  
|<   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33   34   35   36   37   38   39   40   41  
42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   >>   >|  
s on the celluloses themselves previously isolated by other processes showed that they were profoundly and variably attacked by the 'Lange' treatment, wood cellulose losing 50 per cent. of its weight, and filter paper (cellulose) losing 15 per cent. Further, a specimen of jute yielded 58 per cent. of cellulose by this method instead of the normal 78 per cent. It was also found that the celluloses isolated by the process, when subjected to a second treatment, underwent a further large conversion into soluble derivatives, and in a third treatment further losses of 5-10 per cent were obtained. The authors attach value, notwithstanding, to the process which they state to yield an 'approximately pure cellulose,' and they describe a modified method embodying the improvements in detail resulting from their investigation. _Gabriel's_ method of heating with a glycerin solution of alkaline hydrate is a combination of 'Hoenig' and 'Lange.' An extended investigation showed as in the case of the latter that the celluloses themselves are more or less profoundly attacked by the treatment--further that the celluloses isolated from lignocelluloses and other complex raw materials are much 'less pure' than those obtained by the Lange process. Thus, notably in regard to furfural yielding constituents, the latter yield 1-2 p.ct. furfural, whereas _specimens of 'jute cellulose'_ obtained by the Gabriel process were found to yield _9 to 13 p.ct. furfural_. _Cross and Bevan._--Chlorination process yielded in the hands of the authors results confirming the figures given in 'Cellulose' for yield of cellulose. Investigation of the products for yield of furfural, gave 9 p.ct. of this aldehyde showing the presence of celluloses, other than the normal type. _Conclusions._--The subjoined table gives the mean numerical results for yield of end-product or 'cellulose' by the various methods. In the case of the 'celluloses' the results are those of the further action of the several processes on the end-product of a previous process. | Methods | F. Schulze | Weende | Lange | Gabriel | Cross | | | | | and Bevan -------------------------------------------------------------------------- Wood cellulose | 98.51 | 91.52 | 48.22 | 55.93 | -- Filter paper cellulose | 99.62 | 95.63 | 78.17 | 79.77 | -- Swedish filte
PREV.   NEXT  
|<   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33   34   35   36   37   38   39   40   41  
42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   >>   >|  



Top keywords:

cellulose

 

process

 

celluloses

 

treatment

 

furfural

 
Gabriel
 

method

 

isolated

 

results

 

obtained


authors
 

product

 

investigation

 

processes

 

showed

 

losing

 

profoundly

 
attacked
 

normal

 

yielded


showing

 

products

 

aldehyde

 

constituents

 

Chlorination

 

specimens

 
presence
 
confirming
 

Investigation

 
Cellulose

figures

 

Filter

 

Swedish

 
numerical
 

Conclusions

 

subjoined

 

methods

 

yielding

 
Schulze
 

Weende


Methods

 

previous

 

action

 

glycerin

 

conversion

 

underwent

 
subjected
 
soluble
 

derivatives

 

attach