FREE BOOKS

Author's List




PREV.   NEXT  
|<   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80  
81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   >>   >|  
ammonia. In this reagent also the China silk dissolved, and the Tussah silk as well as the lustra-celluloses underwent no appreciable change. 6. _An ammoniacal solution of nickel oxide_ was prepared by dissolving the precipitated hydrated oxide in concentrated ammonia. The China silk was dissolved by this reagent; Tussah silk and the lustra-celluloses entirely resisted its action. 7. _Fehling's solution_ is a solvent of the natural silks, but is without action on the lustra-celluloses. 8. _Chromic acid_--20 p.ct. CrO_{3}--solution dissolves both the natural silks and the lustra-celluloses at the boiling temperature of the solution. 9. _Millon's reagent_, at the boiling solution, colours the natural silks violet: the lustra-celluloses give no reaction. 10. _Concentrated nitric acid_ attacks the natural silks powerfully in the cold; the lustra-celluloses dissolve on heating. 11. _Iodine solution_ (I in KI) colours the China silk a deep brown, Tussah a pale brown; the celluloses from collodion are coloured at first brown, then blue. The Pauly product, on the other hand, does not react. 12. _Diphenylamine sulphate._--A solution of the base in concentrated sulphuric acid colours the natural silks a brown; the collodion 'silks' give a strong blue reaction due to the presence of residual nitro-groups. The Pauly product is not affected. 13. _Brucin sulphate_ in presence of concentrated sulphuric acid colours the natural silks only slightly (brown); the collodion 'silks' give a strong red colouration. The Pauly product again is without reaction. 14. _Water._--The natural silks do not soften in the mouth as do the lustra-celluloses. 15. _Water of condition_ was determined by drying at 100 deg.; the following percentages resulted (a). The percentages of water (b) taken up from the atmosphere after forty-three hours' exposure were: (a) (b) China (raw) silk 7.97 2.24 Tussah silk 8.26 5.00 Lustra-celluloses: Chardonnet (Besancon) 10.37 5.64 " Spreitenbach 11.17 5.77 Lehner 10.71 5.97 Pauly 10.04 6.94 16. _Behaviour on heating at 200 deg.._--After two hours' heating at this temperature the following changes were noted: China silk Much discoloured (brown). Tussah silk Scarcely affec
PREV.   NEXT  
|<   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80  
81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   >>   >|  



Top keywords:

celluloses

 

natural

 

lustra

 

solution

 

Tussah

 

colours

 
concentrated
 

product

 

heating

 

reaction


collodion

 

reagent

 
sulphate
 

ammonia

 

boiling

 

percentages

 

temperature

 
presence
 
action
 

dissolved


sulphuric

 
strong
 

resulted

 
determined
 
colouration
 

slightly

 

soften

 

atmosphere

 
drying
 

condition


Behaviour

 

Lehner

 

Scarcely

 

discoloured

 

Brucin

 

exposure

 

Spreitenbach

 

Besancon

 

Lustra

 
Chardonnet

dissolves

 
Concentrated
 

nitric

 

violet

 
Millon
 

underwent

 

appreciable

 

Chromic

 
resisted
 

prepared