FREE BOOKS

Author's List




PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115  
116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   >>   >|  
he Polyporus cellulose is correlated with its exceptionally low nitrogen. By actual isolation of a crystalline dextrorotary sugar, by preparations of osazone and conversion into saccharic acid, it was proved that dextrose was the main product of hydrolysis. The second main product was shown to be acetic acid, the yield of which amounted to 8 p.ct. in several cases. Generally, therefore, it is proved that the more resistant tissue constituents of the fungi are not cellulose, but a complex of carbohydrates and nitrogenous groups in combination, the former being resolved into glucoses by acid hydrolysis, and the latter yielding acetic acid as a characteristic product of resolution together with the nitrogenous groups in the form of an uncrystallisable syrup. In the further prosecution of these investigations (2) the author proceeded from the supposition of the identity of the nitrogenous complex of the original with chitin, and adopted the method of Ledderhose (Ztschr. Physiol. Chem. 2, 213) for the isolation of glucosamin hydrochloride, which he succeeded in obtaining in the crystalline form. In the meantime E. Gilson had shown that these tissue substances in 'fusion' with alkaline hydrates yield a residue of a nitrogenous product (C_{14}H_{28}N_{2}O_{10}), which is soluble in dilute acids [Recherches Chim. sur la Membrane Cellulaire des Champignons, La Cellule, v. II, pt. 1]. This residue, which was termed mycosin by Gilson, has been similarly isolated by the author. It is proved, therefore, that the tissues of the fungi do contain a product resembling chitin. [See also Gilson, Compt. Rend. 120, 1000.] This constituent is in intimate union with the carbohydrate complex, which is resolved similarly to the hemicelluloses. Various intermediate terms of the hydrolytic series have been isolated. But the only fully identified product of resolution is the dextrose which finally results. UEBER DIE KOHLENHYDRATE D. HEFE. E. SALKOWSKI (Berl. Ber., 27, 3325). ~ON THE CARBOHYDRATES OF YEAST.~ The author has isolated the more resistant constituents of the cell-membrane by boiling with dilute alkalis, and exhaustively purifying with alcohol and ether. The residue was only a small percentage (3-4 p.ct) of the original, and retained only 0.45 p.ct. N. It was heated in a digester with water at 2-3 atm. steam-pressure, and thus resolved into approximately equal portions of soluble cellulose (a) and insoluble (b). The l
PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115  
116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   >>   >|  



Top keywords:

product

 

nitrogenous

 

proved

 

residue

 

isolated

 

author

 
resolved
 

complex

 

Gilson

 

cellulose


original

 

resolution

 
groups
 

resistant

 

tissue

 

constituents

 

chitin

 
similarly
 
dilute
 

soluble


acetic

 
crystalline
 

dextrose

 
isolation
 
hydrolysis
 

Various

 

series

 

hydrolytic

 
intermediate
 

identified


KOHLENHYDRATE

 

results

 

finally

 

conversion

 

hemicelluloses

 

intimate

 

tissues

 

Polyporus

 

osazone

 
termed

mycosin

 
preparations
 

resembling

 

constituent

 
carbohydrate
 

digester

 

heated

 

retained

 
insoluble
 

portions