FREE BOOKS

Author's List




PREV.   NEXT  
|<   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133  
134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>  
_Ferric Ferricyanide Reaction._--Increase of weight due to blue cyanide fixed (1) 75 p.ct., (2) 96 p.ct. Ratio, Fe : CN = 1 : 2, 4. _Hydroxyl Reactions._--In the formation of nitric esters and in the sulphocarbonate reaction the substance gave results similar to those obtaining for the jute fibre. These results establish the general identity of this peculiar product of plant life with the lignocelluloses, at the same time that they show that certain of the colour reactions supposed to characterise the lignocelluloses are due to by-products which may or may not be present. (p. 172) ~Composition of Elder Pith.~--In a systematic investigation of the celluloses in relation to function we shall have to give special attention to the parenchymatous tissues of all kinds. These are, for structural reasons, not easily isolated, for which reason and their generally 'inferior' functions they do not present themselves to chemical observation in the same obvious way as do their fibrous relatives. The pith of the elder, however, _is_ readily obtained in convenient masses, and a preliminary investigation of the entire tissue has established the following points: The _reactions_ of the tissue are in all respects those of the lignocelluloses. _Composition._--Ash, 2.2 p.ct.; moisture in air-dry state, 12.3 p.ct. Alkaline hydrolysis (loss): (a) 14.77, (b) 17.84. Cellulose (yield), 52.33 p.ct. Nitrate-reaction complicated by secondary reactions and yields low, 90.95 p.ct. _Sulphocarbonate reaction:_ Resists the treatment, less than 10 p.ct. passes into solution. _Furfural._--The original tissue yields 7.13 p.ct.; the residue from alkaline hydrolysis (b) 5.40 p.ct. This tissue is, therefore, a lignocellulose having the chemical characteristics typical of the group, but of less resistance to hydrolytic actions. The investigation will be prosecuted in reference to the cause of differentiation in this latter respect. Probably the pectocelluloses are represented in the tissue. ~The Insoluble Carbohydrates of Wheat (grain).~ H. C. SHERMAN (J. Amer. Chem. Soc., 1897, 291). (p. 171) This is a study of the constituents of the cell-walls of wheat grain. Bran was taken as the most convenient form of the raw material, being freed from starch by treatment with malt extract, and further treated (1) with cold dilute ammonia, (2) cold dilute soda lye (2 p.ct. NaOH), and (3) boiling 0.1 p.ct. NaOH. The product retained only 1.25 p
PREV.   NEXT  
|<   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133  
134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>  



Top keywords:

tissue

 

reaction

 

investigation

 

lignocelluloses

 

reactions

 

product

 

treatment

 

convenient

 

yields

 

hydrolysis


Composition

 

chemical

 

present

 

results

 

dilute

 

lignocellulose

 

original

 

solution

 
Furfural
 

extract


alkaline

 
treated
 

ammonia

 

residue

 

retained

 

Nitrate

 

complicated

 

Cellulose

 

secondary

 
boiling

characteristics
 

passes

 

Resists

 

Sulphocarbonate

 
SHERMAN
 
constituents
 
material
 

actions

 
prosecuted
 

reference


hydrolytic

 

starch

 

resistance

 

differentiation

 

Insoluble

 

Carbohydrates

 

represented

 

pectocelluloses

 

respect

 

Probably