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the excess of OH^{-} ions from these bases also diminishes the hydrolytic action of water. This indicator is affected by even so weak an acid as carbonic acid, which must be removed by boiling the solution before titration. It is the indicator most generally employed for the titration of organic acids. In general, it may be stated that when a strong acid, such as hydrochloric, sulphuric or nitric acid, is titrated against a strong base, such as sodium hydroxide, potassium hydroxide, or barium hydroxide, any of these indicators may be used, since very little hydrolysis ensues. It has been noted above that the color change does not occur exactly at theoretical neutrality, from which it follows that no two indicators will show exactly the same end-point when acids and alkalis are brought together. It is plain, therefore, that the same indicator must be employed for both standardization and analysis, and that, if this is done, accurate results are obtainable. The following table (Note 1) illustrates the variations in the volume of an alkali solution (tenth-normal sodium hydroxide) required to produce an alkaline end-point when run into 10 cc. of tenth-normal sulphuric acid, diluted with 50 cc. of water, using five drops of each of the different indicator solutions. ==================================================================== | | | | INDICATOR | N/10 | N/10 |COLOR IN ACID|COLOR IN ALKA- | H_{2}SO_{4}| NaOH |SOLUTION |LINE SOLUTION _______________|____________|__________|_____________|______________ | cc. | cc. | cc. | Methyl orange | 10 | 9.90 | Red | Yellow Lacmoid | 10 | 10.00 | Red | Blue Litmus | 10 | 10.00 | Red | Blue Rosalic acid | 10 | 10.07 | Yellow | Pink Phenolphthalein| 10 | 10.10 | Colorless | Pink ==================================================================== It should also be stated that there are occasionally secondary changes, other than those outlined above, which depend upon the temperature and concentration of the solutions in which the indicators are used. These changes may influence the sensitiveness of an indicator. It is important, therefore, to take pains to use approximately the same volume of solution when standardizing that is likely to be emplo
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