FREE BOOKS

Author's List




PREV.   NEXT  
|<   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73  
74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   >>   >|  
ows the variation in resistance. [Fig. 26 Graph: Changes in internal resistance during charge and discharge] The resistance as measured between the terminals of a cell is made up of several factors as follows: 1. Grids. This includes the resistance of the terminals, connecting links, and the framework upon which the active materials are pasted. This is but a small part of the total resistance, and does not undergo any considerable change during charge and discharge. It increases slightly as the temperature of the grids rises. 2. Electrolyte. This refers to the electrolyte between the plates, and varies with the amount of acid and with temperature. As mentioned in the preceding chapter, a mixture of acid and water in which the acid composes thirty per cent of the electrolyte has the minimum resistance. Diluting or increasing the concentration of the electrolyte will both cause an increase in resistance from the minimum I value. The explanation probably lies in the degree to which the acid is split up into "ions" of hydrogen (H), and sulphate (SO4). These "ions" carry the current through t he electrolyte. Starting with a certain amount of acid, let us see how the ionization progresses. With very concentrated acid, ionization does not take place, and hence, there are no ions to carry current. As we mix the acid with water, ionization occurs. The more water used, the more ions, and hence, the less the resistance, because the number of ions available to carry the current increases. The ionization in creases to a certain maximum degree, beyond which no more ions are formed. It is probable that an electrolyte containing thirty per cent of acid is at its maximum degree of ionization and hence its lowest resistance. If more water is now added, no more ions are formed. Furthermore, the number of ions per unit volume of electrolyte will now decrease on account of the increased amount of water. There Will therefore be fewer ions per unit volume to carry the current, and the resistance of the electrolyte increases. With an electrolyte of a given concentration, an increase of temperature will cause a decrease in resistance. A decrease in temperature will, of course, cause an increase in resistance. It is true, in general, that the resistance of the electrolyte is about half of the total resistance of the cell. The losses due to this resistance generally form only one per cent of the total losses, and area practically
PREV.   NEXT  
|<   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73  
74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   >>   >|  



Top keywords:
resistance
 

electrolyte

 

ionization

 

temperature

 

current

 

increases

 
decrease
 
degree
 
increase
 

amount


thirty

 

terminals

 

minimum

 
concentration
 

charge

 

number

 

discharge

 

volume

 

formed

 

maximum


losses

 

variation

 

occurs

 

generally

 
creases
 

progresses

 

practically

 

concentrated

 
Furthermore
 

increased


account

 

probable

 
general
 

lowest

 
internal
 

Electrolyte

 

slightly

 

refers

 
mentioned
 

varies


factors
 
plates
 

change

 

connecting

 

pasted

 

materials

 
active
 

considerable

 

undergo

 

includes