FREE BOOKS

Author's List




PREV.   NEXT  
|<   437   438   439   440   441   442   443   444   445   446   447   448   449   450   451   452   453   454   455   456   457   458   459   460   461  
462   463   464   465   466   467   468   469   470   471   472   473   474   475   476   477   478   479   480   481   482   483   484   485   486   >>   >|  
ily soluble in water and alcohol, and is thrown out of its aqueous solution by the addition of calcium chloride. Potassium bichromate and sulphuric acid oxidize it to carbon dioxide and acetic acid, while alkaline potassium permanganate oxidizes it to carbon dioxide. The calcium salt, Ca(C_4H_7O_2)_2.H_2O, is less soluble in hot water than in cold. _Isobutyric acid_ is found in the free state in carobs (_Ceratonia siliqua_) and in the root of _Arnica dulcis_, and as an ethyl ester in croton oil. It may be artificially prepared by the hydrolysis of isopropylcyanide with alkalies, by the oxidation of isopropyl alcohol with potassium bichromate and sulphuric acid (I. Pierre and E. Puchot, _Ann. de chim. et de phys._, 1873, [4] 28, p. 366), or by the action of sodium amalgam on methacrylic acid, CH_2.C(CH_3).COOH. It is a liquid of somewhat unpleasant smell, boiling at 155.5 deg. C. Its specific gravity is 0.9697 (0 deg.). Heated with chromic acid solution to 140 deg. C., it gives carbon dioxide and acetone. Alkaline potassium permanganate oxidizes it to [alpha]-oxyisobutyric acid, (CH_3)_2.C(OH).COOH, whilst concentrated nitric acid converts it into dinitroisopropane. Its salts are more soluble in water than those of the normal acid. BUXAR, or BAXAR, a town of India, in the district of Shahabad, Bengal, on the south bank of the Ganges, and on the East Indian railway. Pop. (1901) 13,945. There is a dismantled fort of small size which was important from its commanding the Ganges. A celebrated victory was gained here on the 23rd of October 1764 by the British forces under Major (afterwards Sir Hector) Munro, over the united armies of Shuja-ud-Dowlah and Kasim Ali Khan. The action raged from 9 o'clock till noon, when the enemy gave way. Pursuit was, however, frustrated by Shuja-ud-Dowlah sacrificing a part of his army to the safety of the remainder. A bridge of boats had been constructed over a stream about 2 m. distant from the field of battle, and this the enemy destroyed before their rear had passed over. Through this act 2000 troops were drowned, or otherwise lost; but destructive as was this proceeding, it was, said Major Munro, "the best piece of generalship Shuja-ud-Dowlah showed that day, because if I had crossed the rivulet with the army, I should either have taken or drowned his whole army in the Karamnasa, and come up with his treasure and jewels, and Kasim Ali Khan's jewels, which I was informed amounted to betwee
PREV.   NEXT  
|<   437   438   439   440   441   442   443   444   445   446   447   448   449   450   451   452   453   454   455   456   457   458   459   460   461  
462   463   464   465   466   467   468   469   470   471   472   473   474   475   476   477   478   479   480   481   482   483   484   485   486   >>   >|  



Top keywords:

potassium

 

carbon

 
dioxide
 

Dowlah

 
soluble
 

drowned

 

calcium

 

bichromate

 

sulphuric

 

jewels


solution

 
alcohol
 

Ganges

 

action

 
oxidizes
 
permanganate
 
Pursuit
 

frustrated

 

British

 
celebrated

victory
 

gained

 

commanding

 

important

 
dismantled
 
October
 

united

 

armies

 

Hector

 

forces


crossed
 

rivulet

 

showed

 

proceeding

 

generalship

 

treasure

 

informed

 

amounted

 

betwee

 
Karamnasa

destructive

 
stream
 
distant
 

constructed

 

safety

 
remainder
 

bridge

 
battle
 

destroyed

 
troops