FREE BOOKS

Author's List




PREV.   NEXT  
|<   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140  
141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   >>   >|  
_Heliotropin_, which possesses the characteristic odour of heliotrope, is prepared artificially from safrol. It crystallises in small prisms melting at 86 deg. C. _Hyacinth._--Most of the articles sold under this name are secret blends of the different makers. Styrolene has an odour very much resembling hyacinth, and probably forms the basis of most of these preparations, together with terpineol, and other artificial bodies. The properties of the oil vary considerably for different makes. _Ionone_, a ketone first prepared by Tiemann, and having when diluted a pronounced violet odour. It is prepared by treating a mixture of citral and acetone with barium hydrate, and distilling in vacuo. Two isomeric ketones, [alpha]-ionone and [beta]-ionone, are produced, the article of commerce being usually a mixture of both. The two ketones have the following properties:-- Alpha-ionone.--Specific gravity at 15 deg. C., 0.9338; refractive index at 16.5 C., 1.50048 (Chuit); optically it is inactive. Beta-ionone.--Specific gravity at 15 deg. C., 0.9488; refractive index at 16.8 deg. C., 1.52070 (Chuit); optically it is inactive also. The product is usually sold in 10 or 20 per cent. alcoholic solution ready for use. _Jasmine._--This is one of the few cases in which the artificial oil is probably superior to that obtained from the natural flowers, possibly due to the extreme delicacy of the odour, and its consequent slight decomposition during preparation from the flowers. The chemical composition of the floral perfume has been very exhaustively studied, and the artificial article now on the market may be described as a triumph of synthetical chemistry. Among its constituents are benzyl acetate, linalyl acetate, benzyl alcohol, indol, methyl anthranilate, and a ketone jasmone. _Linalol_, the alcohol forming the greater part of linaloe and bois de rose oils, and found also in lavender, neroli, petitgrain, bergamot, and many other oils. The article has the specific gravity at 15 deg. C., 0.870-0.876; optical rotation, -12 deg. to -14 deg.; refractive index at 20 deg. C., 1.463-1.464; and when estimated by acetylation, yields about 70 per cent. of alcohols. _Linalyl acetate_, or _artificial bergamot oil_, is the ester formed when linalol is treated with acetic anhydride. It possesses a bergamot-like odour, but it is doubtful whether its value is commensurate with its greatly increased price over that of ordinary bergamo
PREV.   NEXT  
|<   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140  
141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   >>   >|  



Top keywords:

ionone

 

artificial

 
gravity
 

acetate

 
bergamot
 

refractive

 

article

 

prepared

 

benzyl

 

optically


mixture

 
properties
 

inactive

 

flowers

 
possesses
 
ketone
 
ketones
 

Specific

 

alcohol

 
synthetical

chemistry
 

constituents

 

anthranilate

 

methyl

 
linalyl
 
market
 

preparation

 

chemical

 

composition

 

floral


decomposition
 

delicacy

 

consequent

 

slight

 

perfume

 

exhaustively

 

studied

 

triumph

 

linalol

 
formed

treated

 
acetic
 
anhydride
 

Linalyl

 

yields

 
alcohols
 

ordinary

 
bergamo
 

increased

 
greatly