FREE BOOKS

Author's List




PREV.   NEXT  
|<   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95  
96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   >>   >|  
you must rob it of some of its hydrogen. Thus C_{6}H_{5} is a group that would exist only for a moment, since it has a great appetite for H, and we may say this appetite would go the length of at once absorbing either one atom of H (hydrogen) or of some similar substance or group having a similar appetite. Suppose, now, I place some benzene, C_{6}H_{6}, in a flask, and add some nitric acid, which, as we said, is NO_{2}OH. On warming the mixture we may say a tendency springs up in that OH of the nitric acid to effect union with an H of the C_{6}H_{6} (benzene) to form HOH (water), when an appetite is at once left to the remainder, C_{6}H_{5}--on the one hand, and the NO_{2}--on the other, satisfied by immediate union of these residues to form a substance C_{6}H_{6}NO_{2}, nitro-benzene or "essence of mirbane," smelling like bitter almonds. This is the first step in the formation of aniline. I think I have told you that if we treat zinc scraps with water and vitriol, or water with potassium, we can rob that water of its oxygen and set free the hydrogen. It is, however, a singular fact that if we liberate a quantity of fresh hydrogen amongst our nitrobenzene C_{6}H_{5}NO_{2}, that hydrogen tends to combine, or evinces an ungovernable appetite for the O_{2} of that NO_{2} group, the tendency being again to form water H_{2}O. This, of course, leaves the residual C_{6}H_{5}N: group with an appetite, and only the excess of hydrogen present to satisfy it. Accordingly hydrogen is taken up, and we get C_{6}H_{5}NH_{2} formed, which is aniline. I told you that ammonia is NH_{3}, and now in aniline we find an ammonia derivative, one atom of hydrogen (H) being replaced by the group C_{6}H_{5}. I will now describe the method of preparation of a small quantity of aniline, in order to illustrate what I have tried to explain in theory. Benzene from coal-tar is warmed with nitric acid in a flask. A strong action sets in, and on adding water, the nitrobenzene settles down as a heavy oil, and the acid water can be decanted off. After washing by decantation with water once or twice, and shaking with some powdered marble to neutralise excess of acid, the nitrobenzene is brought into contact with fresh hydrogen gas by placing amongst it, instead of zinc, some tin, and instead of vitriol, some hydrochloric acid (spirits of salt). To show you that aniline is formed, I will now produce a violet colour with it, which only aniline will give. This
PREV.   NEXT  
|<   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95  
96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   >>   >|  



Top keywords:

hydrogen

 

appetite

 

aniline

 
benzene
 

nitrobenzene

 

nitric

 

quantity

 

vitriol

 
excess
 

tendency


formed

 
similar
 

substance

 
ammonia
 

present

 

Benzene

 

explain

 
satisfy
 

theory

 

Accordingly


preparation

 
replaced
 

derivative

 

describe

 

method

 

illustrate

 
placing
 

contact

 
marble
 

neutralise


brought

 

hydrochloric

 

spirits

 

violet

 
colour
 
produce
 
powdered
 

shaking

 

adding

 

settles


action

 

strong

 
warmed
 

washing

 

decantation

 

decanted

 
effect
 

springs

 

warming

 

mixture