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air, and so on, gradually oxidise, the great preponderance of iron on the fibre changing to a kind of iron-rust, corroding the fibres in the process, and thus at once accounting for the change to the ugly brownish shade, and to the rubbing off and rapid wearing away of the already too thin superficial coating of dyed felt fibre. In the final spells of dyeing in the dye-beck already referred to, tolerably thick with black precipitate or mud, the application of black to the hat-forms begins, I fear, to assume at length a too close analogy to another blacking process closely associated with a pair of brushes and the time-honoured name of Day & Martin. With that logwood black fibre, anyone could argue as to a considerable proportion of the dye rubbing, wearing, or washing off. Thus, then, we have the second cause of the deterioration of the black, for the colour could not go into the fibre, and so it was chiefly laid or plastered on. You can also see that a logwood black hat dyer may well make the boast, and with considerable appearance of truth, that for the purposes of the English hat manufacturers, logwood black dyeing is the most appropriate, _i.e._ for the dyeing of highly proofed and stiff goods, but as to the permanent character of the black colour on those stiff hats, there you have quite another question. I firmly believe that in order to get the best results either with logwood black or "aniline blacks," it is absolutely necessary to have in possession a more scientific and manageable process of proofing. Such a process is that invented by F.W. Cheetham (see Lecture VII. p. 66). In the dyeing of wool and felt with coal-tar colours, it is in many cases sufficient to add the solution of the colouring matters to the cold or tepid water of the dye-bath, and, after introducing the woollen material, to raise the temperature of the bath. The bath is generally heated to the boiling-point, and kept there for some time. A large number of these coal-tar colours show a tendency of going so rapidly and greedily on to the fibre that it is necessary to find means to restrain them. This is done by adding a certain amount of Glauber's salts (sulphate of soda), in the solution of which coal-tar colours are not so soluble as in water alone, and so go more slowly, deliberately, and thus evenly upon the fibre. It is usually also best to dye in a bath slightly acid with sulphuric acid, or to add some bisulphate of soda. There is anothe
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