FREE BOOKS

Author's List




PREV.   NEXT  
|<   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67  
68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   >>   >|  
thyl Pentoses_ (C_{6}H_{12}O_{5}) Aldoses--_d_- and _l_-Arabinose Aldoses--Rhamnose _d_- and _l_-Xylose Fucose _l_-Ribose Rhodeose _l_-Lyxose Chinovose _Hexoses_ (C_{6}H_{12}O_{6}) Mannitol series Dulcitol series Aldoses--_d_- and _l_-Glucose _d_- and _l_-Galactose _d_- and _l_-Mannose _d_- and _l_-Talose _d_- and _l_-Gulose _d_- and _l_-Idose _d_-Altrose _d_-Allose Ketoses-- _d_-Fructose _d_-Tagatose _d_-Sorbose _Heptoses_ _Octoses_ _Nonoses_ (C_{7}H_{14}O_{7}) (C_{8}H_{16}O_{8}) (C_{9}H_{18}O_{9}) Glucoheptose Gluco-octose Glucononose Mannoheptose Manno-octose Mannononose Galactoheptose Galacto-octose Persuelose Sedoheptose The hexoses are by far the most important group of monosaccharides. They are undoubtedly the first products of photosynthesis, and all the other carbohydrates may be considered to be derived from them by condensation. Because of their biochemical significance and their immense importance as the fundamental substances for all plant and animal energy-producing materials, the following detailed studies of their chemical composition and molecular configuration are fully warranted. That all the hexoses contain five alcoholic groups is proved by the experimental evidence that each one forms a penta-ester, by uniting with five acid radicals, when treated with mineral or organic acids under proper conditions. Thus, glucose penta-acetate, penta-nitrate, penta-benzoate, etc., have all been prepared. The presence of the aldehyde group is proved by the fact that all aldohexoses have been converted, by gentle oxidation, into pentaoxy-monobasic acids, and the ketohexoses broken down into shorter chain compounds by similar gentle oxidations; these reactions being characteristic of compounds containing an aldehyde and a ketone group respectively. This experimental evidence establishes the nature of the characteristic groups in the molecule, in each case. The molecular configurations illustrated in the following table are those suggested by Emil Fische
PREV.   NEXT  
|<   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67  
68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   >>   >|  



Top keywords:

octose

 

Aldoses

 

groups

 

hexoses

 
aldehyde
 

gentle

 

compounds

 
experimental
 

proved

 
series

characteristic

 

evidence

 
molecular
 

proper

 

warranted

 
conditions
 

glucose

 
mineral
 

acetate

 

alcoholic


uniting

 

organic

 

treated

 
radicals
 

establishes

 

nature

 

ketone

 

molecule

 

suggested

 

Fische


configurations

 

illustrated

 

reactions

 

aldohexoses

 

converted

 

oxidation

 
presence
 
benzoate
 
prepared
 

pentaoxy


monobasic
 

similar

 

oxidations

 

shorter

 

ketohexoses

 

broken

 

nitrate

 

fundamental

 

Sorbose

 

Heptoses