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d and a base are brought together in solution in proper proportion, the characteristic properties of each disappear. The solution tastes neither sour nor brackish; it has no effect upon indicators. There can therefore be neither hydrogen nor hydroxyl ions present in the solution. A study of reactions of this kind has shown that the hydrogen ions of the acid combine with the hydroxyl ions of the base to form molecules of water, water being a substance which is not appreciably dissociated into ions. This action of an acid on a base is called _neutralization_. The following equations express the neutralization of the three acids by three bases, water being formed in each case. Na^{+}, OH^{-} + H^{+}, Cl^{-} = Na^{+}, Cl^{-} + H_{2}O. K^{+}, OH^{-} + H^{+}, NO_{3}^{-} = K^{+}, NO_{3}^{-} + H_{2}O. Ca^{++}, (OH)_{2}^{--} + H_{2}^{++}, SO_{4}^{--} = Ca^{++}, SO_{4}^{--} + 2H_{2}O. DEFINITION: _Neutralization consists in the union of the hydrogen ion of an acid with the hydroxyl ion of a base to form water._ ~Salts.~ It will be noticed that in neutralization the anion of the acid and the cation of the base are not changed. If, however, the water is expelled by evaporation, these two ions slowly unite, and when the water becomes saturated with the substance so produced, it separates in the form of a solid called a _salt_. DEFINITION: _A salt is a substance formed by the union of the anion of an acid with the cation of a base._ ~Characteristics of salts.~ (1) From the definition of a salt it will be seen that there is no element or group of elements which characterize salts. (2) Salts as a class have no peculiar taste. (3) In the absence of all other substances they are without action on indicators. (4) When dissolved in water they form two kinds of ions. ~Heat of neutralization.~ If neutralization is due to the union of hydrogen ions with hydroxyl ions, and nothing more, it follows that when a given weight of water is formed in neutralization, the heat set free should always be the same, no matter from what acid and base the two kinds of ions have been supplied. Careful experiments have shown that this is the case, provided no other reactions take place at the same time. When 18g. of water are formed in neutralization, 13,700 cal. of heat are set free. This is represented in the equations Na^{+}, OH^{-} + H^{+}, Cl^{-} = Na^{+}, C
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