FREE BOOKS

Author's List




PREV.   NEXT  
|<   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139  
140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   >>   >|  
In the preparation of carbon disulphide an electrical furnace is employed, such as is represented in Fig. 45. The furnace is packed with carbon C, and this is fed in through the hoppers B, as fast as that which is present in the hearth of the furnace is used up. Sulphur is introduced at A, and at the lower ends of the tubes it is melted by the heat of the furnace and flows into the hearth as a liquid. An electrical current is passed through the carbon and melted sulphur from the electrodes E, heating the charge. The vapors of carbon disulphide pass up through the furnace and escape at D, from which they pass to a suitable condensing apparatus. ~Comparison of sulphur and oxygen.~ A comparison of the formulas and the chemical properties of corresponding compounds of oxygen and sulphur brings to light many striking similarities. The conduct of hydrosulphuric acid and water toward many substances has been seen to be very similar; the oxides and sulphides of the metals have analogous formulas and undergo many parallel reactions. Carbon dioxide and disulphide are prepared in similar ways and undergo many analogous reactions. It is clear, therefore, that these two elements are far more closely related to each other than to any of the other elements so far studied. ~Selenium and tellurium.~ These two very uncommon elements are still more closely related to sulphur than is oxygen. They occur in comparatively small quantities and are usually found associated with sulphur and sulphides, either as the free elements or more commonly in combination with metals. They form compounds with hydrogen of the formulas H_{2}Se and H_{2}Te; these bodies are gases with properties very similar to those of H_{2}S. They also form oxides and oxygen acids which resemble the corresponding sulphur compounds. The elements even have allotropic forms corresponding very closely to those of sulphur. Tellurium is sometimes found in combination with gold and copper, and occasions some difficulties in the refining of these metals. The elements have very few practical applications. ~Crystallography.~ In order to understand the difference between the two kinds of sulphur crystals, it is necessary to know something about crystals in general and the forms which they may assume. An examination of a large number of crystals has shown that although they may differ much in geometric form, they can all be c
PREV.   NEXT  
|<   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139  
140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   >>   >|  



Top keywords:

sulphur

 

elements

 

furnace

 

oxygen

 
carbon
 
compounds
 

formulas

 

crystals

 

closely

 

similar


metals

 

disulphide

 

sulphides

 

hearth

 

undergo

 

properties

 

analogous

 
combination
 

reactions

 

oxides


melted
 
related
 

electrical

 

bodies

 

commonly

 

quantities

 

comparatively

 
preparation
 

hydrogen

 

resemble


copper

 
assume
 

examination

 
general
 

number

 

geometric

 
differ
 
uncommon
 

occasions

 

allotropic


Tellurium

 

difficulties

 

refining

 

understand

 

difference

 

Crystallography

 
applications
 

practical

 
condensing
 

apparatus