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sh the same weight of acid? 8. 100 l. of nitrogen peroxide were dissolved in water and neutralized with sodium hydroxide. What substances were formed and how much of each?(1 l. nitrogen peroxide weighs 2.05 grams.) 9. How many liters of nitrous oxide, measured under standard conditions, can be prepared from 10 g. of ammonium nitrate? 10. What weight of copper is necessary to prepare 50 l. of nitric oxide under standard conditions? 11. (a) Calculate the percentage composition of the oxides of nitrogen. (b) What important law does this series of substances illustrate? 12. Write the equations representing the reactions between ammonium hydroxide, and sulphuric acid and nitric acid respectively, in accordance with the theory of electrolytic dissociation. 13. In the same way, write the equations representing the reactions between nitric acid and each of the following bases: NaOH, KOH, NH_{4}OH, Ca(OH)_{2}. CHAPTER XIII REVERSIBLE REACTIONS AND CHEMICAL EQUILIBRIUM ~Reversible reactions.~ The reactions so far considered have been represented as continuing, when once started, until one or the other substance taking part in the reaction has been used up. In some reactions this is not the case. For example, we have seen that when steam is passed over hot iron the reaction is represented by the equation 3Fe + 4H_{2}O = Fe_{3}O_{4} + 8H. On the other hand, when hydrogen is passed over hot iron oxide the reverse reaction takes place: Fe_{3}O_{4} +8H = 3Fe + 4H_{2}O. The reaction can therefore go in either direction, depending upon the conditions of the experiment. Such a reaction is called a _reversible reaction_. It is represented by an equation with double arrows in place of the equality sign, thus: 3Fe + 4H_{2}O <--> Fe_{3}O_{4} + 8H. In a similar way, the equation N + 3H <--> NH_{3} expresses the fact that under some conditions nitrogen may unite with hydrogen to form ammonia, while under other conditions ammonia decomposes into nitrogen and hydrogen. The conversion of oxygen into ozone is also reversible and may be represented thus: oxygen <--> ozone. ~Chemical equilibrium.~ Reversible reactions do not usually go on to completion in one direction unless the conditions under which the reaction takes place are very carefully chosen. Thus, if iron and steam are confined in a heated tube, the steam acts upon the iron, producing iron oxide and hydrogen. Bu
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