FREE BOOKS

Author's List




PREV.   NEXT  
|<   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76  
77   78   79   80   81   82   83   84   85   86   87   88   89   90   >>  
he design, well defined in all its details, is visible on the back of the paper, which requires an insolation of about two minutes in clear sunshine, and from eight to ten times longer in the shade. In cloudy weather the exposure to light is necessarily very long. As explained before, the luminous action, by reducing the chromic salt in presence of certain organic substances, causes the latter to become insoluble; consequently if, on its removal from the printing frame, the proof be soaked in cold water, for, say, ten minutes, and, placing it on a glass plate or a smooth board, gently rubbed with a brush or a soft rag, the parts of the albumen or gum arabic preparation not acted on will dissolve, leaving behind the black image standing out on the white ground of the paper. This done, and when the unreduced bichromate is washed out in two changes of water, the operation is at an end. As to the theory of this and similar processes, the insolubilization of the bichromate organic substance acted on by light was formerly attributed to the oxidation of the substance by the oxygen evolved during the reduction of the chromic salt into chromic oxide; but from the fact that oxidation generally tends to destroy organic matters, or to increase their solubility, it is more probable that it results from the formation of a peculiar compound of the substance with chromic oxide (J. W. Swan); moreover, gelatine imbued with an alkaline bichromate, then immersed first in a solution of ferrous sulphate and afterwards in hot water, is insolubilized with formation of chromium trioxide, Cr2O7K2+SO4Fe = SO4K2+C2O4Fe+C2O3 (Monckhoven). A similar but inverse action occurs, as shown by Poitevin, when gelatine rendered insoluble by ferric chloride becomes soluble by the transformation, under the influence of light, of the ferric salt into one at the minimum. The writer has improved the above process by simplifying the modus operandi as follows: Instead of compounding the preparation with gum arabic and the coloring matter, the albumen is simply clarified by beating the whites of eggs to a froth, etc., and the paper is coated by floating for one minute, then hung up to dry in a place free from dust. If the reader has any objection for albumenizing his own paper, he can use the albumen paper found in the market for the printing-out silver process generally employed by photographers. The paper is sensitized from the back with the potassi
PREV.   NEXT  
|<   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76  
77   78   79   80   81   82   83   84   85   86   87   88   89   90   >>  



Top keywords:

chromic

 

organic

 

bichromate

 

albumen

 

substance

 

ferric

 
gelatine
 

printing

 
process
 
insoluble

formation

 
oxidation
 
arabic
 

preparation

 
generally
 

similar

 
action
 

minutes

 
Poitevin
 

Monckhoven


occurs

 
inverse
 

chloride

 

influence

 

defined

 

minimum

 

transformation

 

soluble

 

C2O4Fe

 

rendered


Cr2O7K2

 

imbued

 

alkaline

 
details
 
immersed
 

visible

 

solution

 

chromium

 

trioxide

 

insolubilized


ferrous

 

sulphate

 
design
 

reader

 
objection
 
albumenizing
 

employed

 
photographers
 
sensitized
 

potassi