FREE BOOKS

Author's List




PREV.   NEXT  
|<   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102  
103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   >>   >|  
d absorbed within the charcoal, and ceases to be visible as soon as it is submitted to the reducing flame, while the external flame is colored violet; sulphate of potassa, for instance, is reduced by the glowing charcoal into the sulphide. This latter is somewhat volatile, but by passing through the oxidation flame, it is again oxidized into the sulphate. This, being less volatile, sublimes upon the charcoal, but by exposing it again to the flame of reduction, it is reduced and carried off to be again oxidized by its passage through the oxidation flame. Potassa and its compounds give, with soda, borax or microcosmic salt, as well when hot as cold, colorless beads, unless the acid associated with the alkali should itself produce a color. When borax is fused with some pure boracic acid, and sufficient of the oxide of nickel is added, so that the beads appear of a brown color after being cooled, and then the bead thus produced fused with the substance suspected to contain potassa, in the oxidation flame, the brown color is changed to blue. The presence of the other alkalies does not prevent this reaction. As it is not possible to detect potassa compounds with unerring certainty by the blowpipe flame, the the wet method should be resorted to for the purpose of confirming it. The _silicates of potassa_ must be prepared as follows, for analytical purposes by the wet way. Mix one part of the finely powdered substance with two parts of soda (free from potassa), and one part of borax. Fuse the mixture upon charcoal in the oxidation flame to a clear, transparent bead. This is to be exposed again with the pincers to the oxidation flame, to burn off the adhering coal particles. Then pulverize and dissolve in hydrochloric acid to separate the silica; evaporate to dryness, dissolve the residue in water, with the admixture of a little alcohol, and test the filtrate with chloride of platinum for potassa. (_b._) _Soda_ (NaO).--This is one of the most abundant substances, although seldom found free, but combined with chlorine or some other less abundant compound. Soda, its hydrate and salts manifest in general the same properties as their respective potash compounds; but the salts of soda mostly contain crystal water, which leaves the salts if they are exposed to the air, and the salts effervesce. By exposing soda or its compounds upon a platinum wire to the blue flame, a reddish-yellow color is communicated to the external flame
PREV.   NEXT  
|<   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102  
103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   >>   >|  



Top keywords:

potassa

 

oxidation

 

charcoal

 
compounds
 
dissolve
 

exposed

 
platinum
 

abundant

 

substance

 

oxidized


external
 

volatile

 

reduced

 

sulphate

 

exposing

 
powdered
 

residue

 

evaporate

 

separate

 
silica

dryness

 
admixture
 

chloride

 

finely

 

filtrate

 

alcohol

 

hydrochloric

 
violet
 

pincers

 

transparent


mixture

 

adhering

 

pulverize

 

particles

 

colored

 

leaves

 

crystal

 

respective

 

potash

 

reddish


yellow

 

communicated

 

effervesce

 

properties

 

substances

 

seldom

 
reducing
 

ceases

 

visible

 

combined