FREE BOOKS

Author's List




PREV.   NEXT  
|<   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125  
126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>   >|  
it tarnishes. It is easily dissolved by nitric acid, but very slowly by dilute sulphuric or hydrochloric acid, producing hydrogen. _Protoxide of Nickel _(NiO).--It is in the form of small greyish-black octahedrons, or a dark, greenish-grey powder. Its hydrate is a green powder. Both are unalterable in the air, and are soluble in nitric, sulphuric, and hydrochloric acids, to a green liquid. The protoxide is the base of the salts of nickel, which in the anhydrous state are yellow, and when hydrated are green. The soluble neutral salts change blue litmus paper to red. By ignition in the oxidation flame, protoxide of nickel is unaltered. In the reduction flame and upon charcoal, it becomes reduced, and forms a grey adherent powder, which is infusible, and presents the metallic lustre by compression, and is magnetic. Borax dissolves it in the oxidation flame very readily to a clear bead, of a reddish-violet or dark yellow color, but yellow or light red when cold. If there is but a small quantity of the oxide present, it is colorless. If more of the oxide be present, the bead is opaque and dark brown, and appears, while cooling, transparent and dark red. By the addition of a salt of potassa (the nitrate or carbonate) a blue or a dark purple colored bead is produced. The borax bead, in the reduction flame, is grey, turbid, or completely opaque from the reduced metallic particles. After a continued blast, the bead becomes colorless, although the particles are not fused. If the nickel contains cobalt, it will now be visible with its peculiar blue color. Upon charcoal, and by the addition of some tin, the reduction of the oxide of nickel is easily effected, while the reduced nickel fuses with the tin. The oxide of nickel is dissolved by microcosmic salt in the oxidation flame to a clear bead, which appears reddish while hot, but yellow and sometimes colorless when cooling. If a considerable quantity of nickel be present the heated bead is of a brown color, but orange when cooled. In the reduction flame, and upon platinum wire, the color of the bead is orange when cold; but upon charcoal, and with the addition of a little tin, the bead appears grey and opaque. After being submitted to the blowpipe flame all the nickel is reduced, and the bead becomes colorless. Carbonate of soda does not affect it in the oxidation flame, but in the reduction flame and upon charcoal, it is absorbed and reduced, and remains, after washing off
PREV.   NEXT  
|<   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125  
126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>   >|  



Top keywords:

nickel

 

reduction

 

reduced

 
colorless
 
charcoal
 

oxidation

 

yellow

 

opaque

 
present
 

appears


addition
 

powder

 

dissolved

 

metallic

 

hydrochloric

 

nitric

 

sulphuric

 

reddish

 
quantity
 

easily


orange

 

cooling

 

protoxide

 

soluble

 

particles

 

turbid

 

produced

 

completely

 

continued

 

heated


considerable

 

affect

 
cooled
 

Carbonate

 

blowpipe

 

platinum

 

absorbed

 
submitted
 
washing
 

visible


peculiar

 
colored
 

microcosmic

 

remains

 
effected
 
cobalt
 

lustre

 

unalterable

 

hydrate

 

greenish