FREE BOOKS

Author's List




PREV.   NEXT  
|<   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74  
75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   >>   >|  
be used when there is danger of a metallic oxide being reduced, as in this case the metal would alloy with the platinum and spoil the forceps. In this case charcoal should be used for the support. If, however, there be oxides present which are not reduced by the borax, then the platinum loop may be used. Tin is frequently used for the purpose of enabling the bead to acquire a color for an oxide in the reducing flame, by its affinity for oxygen. The oxide, thus being reduced to a lower degree of oxidation, imparts its peculiar tinge to the bead as it cools. The arsenides and sulphides, before being examined, should be roasted, and then heated with the borax bead. The arsenic of the former, it should be observed, will act on the glass tube in which the sublimation is proceeding, if the glass should contain lead. It should be recollected that earths, metallic oxides, and metallic acids are soluble in borax, except those of the easily reducible metals, such as platinum or gold, or of mercury, which too readily vaporize. Also the metallic sulphides, after the sulphur has been driven off. Also the salts of metals, after their acids are driven off by heat. Also the nitrates and carbonates, after their acids are driven off during the fusion. Also the salts of the halogens, such as the chlorides, iodides, bromides, etc., of the metals. Also the silicates, but with great tardiness. Also the phosphates and borates that fuse in the bead without suffering decomposition. The metallic sulphides are insoluble in borax, and many of the metals in the pure state. There are many substances which give clear beads with borax both while hot and cold, but which, upon being heated with the intermittent oxidation flame, become enamelled and opaque. The intermittent flame may be readily attained, not by varying the force of the air from the mouth, but by raising and depressing the bead before the point of the steady oxidating flame. The addition of a little nitrate of potash will often greatly facilitate the production of a color, as it oxidizes the metal. The hot bead should be pressed upon a small crystal of the nitrate, when the bead swells, intumesces, and the color is manifested in the surface of the bead, 6. EXAMINATIONS IN MICROCOSMIC SALT. Microcosmic salt is a better flux for many metallic oxides than borax, as the colors are exhibited in it with more strength and character. Microcosmic salt is the phosphate of soda and a
PREV.   NEXT  
|<   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74  
75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   >>   >|  



Top keywords:

metallic

 

metals

 

driven

 

sulphides

 

reduced

 
platinum
 

oxides

 

intermittent

 

readily

 

nitrate


heated
 

oxidation

 

Microcosmic

 

opaque

 

enamelled

 

attained

 

borates

 
suffering
 

varying

 

decomposition


insoluble

 

substances

 

phosphates

 

MICROCOSMIC

 

EXAMINATIONS

 

intumesces

 
manifested
 
surface
 

character

 
phosphate

strength

 

colors

 

exhibited

 
swells
 

crystal

 

steady

 

oxidating

 

depressing

 
raising
 

addition


tardiness

 

oxidizes

 

pressed

 

production

 

facilitate

 

potash

 
greatly
 
degree
 

oxygen

 

affinity