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a low ignition point. When made at higher temperatures it is much more dense, and its ignition point is considerably higher. Charcoal burns when heated in air, usually without the formation of flame, although a flame is apparent if the temperature be raised. It is characterized by its power of absorbing gases; thus, according to J. Hunter [_Phil. Mag._, 1863 (4), 25, p. 363], one volume of charcoal absorbs (at 0 deg. C. and 760 mm. pressure) 171.7 ccs. of ammonia, 86.3 ccs. of nitrous oxide, 67.7 ccs. of carbon monoxide, 21.2 ccs. of carbon dioxide, 17.9 ccs. of oxygen, 15.2 ccs. of nitrogen, and 4.4 ccs. of hydrogen [see also J. Dewar, _Ann. Chim. Phys._, 1904 (8), 3, p. 5]. It also has the power of absorbing colouring matters from solution. Charcoal is used as a fuel and as a reducing agent in metallurgical processes. The element carbon unites directly with hydrogen to form acetylene when an electric arc is passed between carbon poles in an atmosphere of hydrogen (M. Berthelot); it also unites directly with fluorine, producing, chiefly, carbon tetrafluoride CF4. It burns when heated in an atmosphere of oxygen, forming carbon dioxide, and when heated in sulphur vapour it forms carbon bisulphide (q.v.). When heated with nitrogenous substances, in the presence of carbonated or caustic alkali, it forms cyanides. It combines directly with silicon, at the temperature of the electric furnace, yielding _carborundum_, SiC; and H. Moissan has also shown that it will combine with many metals at the temperature of the electric furnace, to form carbides (q.v.). The specific heat of carbon varies with the temperature the following values having been obtained by H.F. Weber (_Jahresberichte_, 1874, p. 63):-- +-----------------+-----------------+-------------------+ | Diamond. | Graphite. |Porous wood carbon.| +-------+---------+-------+---------+--------+----------+ | t deg.| Sp. Ht. | t deg.| Sp. Ht. | t deg. | Sp. Ht. | +-------+---------+-------+---------+--------+----------+ | -50.5 | 0.0635 | -50.3 | 0.1138 | 0-23 | 0.1653 | | -10.6 | 0.0955 | -10.7 | 0.1437 | 0-99 | 0.1935 | | +10.7 | 0.1128 | +10.8 | 0.1604 | 0-223 | 0-2385 | | 85.5 | 0.1765 | 61.3 | 0.1990 | | | | 206.1 | 0.2733 | 201.6 | 0.2966 | | | | 606.7 | 0.4408 | 641.9 | 0.4454 | | |
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