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ain, North America and elsewhere, are very important beds of ironstone, fire-clay, terra-cotta clay, and occasionally oil shale and alum shale. Oil and gas are of importance in the Lower Carboniferous Pocono sandstone of West Virginia and in the Berea grit of Ohio, where brine also occurs. In the Carboniferous Limestone series, the purer kinds of limestone are used for the manufacture of lime, bleaching powder and similar products, also as a flux in the smelting of iron; some of the less pure varieties are used in making cement. The beds of chert are utilized in the pottery industry, and some of the harder and more crystalline limestones are beautiful marbles, capable of taking a high polish. The sandstones are used for building, and for millstones and grindstones. Within the Carboniferous rocks, but due to the action of various agencies long after their deposition, are important ore formations; such are the Rio Tinto ores of Spain, the lead and zinc ores and some haematite of the Pennine and Mendip hills and other British localities, and many ore regions in the United States. REFERENCES.--For a good general account of the Carboniferous system, see A. Geikie, _Text Book of Geology_, vol. ii. (4th ed., 1903); and for the American development see T.C. Chamberlin and R.D. Salisbury, _Geology_, vol. ii. (1906). These two works give abundant references to the literature of the subject. See also, _Recent Additions to Geological Literature_, published annually by the Geological Society of London since 1893; and _Neues Jahrbuch fur Mineralogie_ (Stuttgart). (J. A. H.) CARBORUNDUM, a silicide of carbon formed by the action of carbon on sand (silica) at high temperatures, which on account of its great hardness is an important abrasive, and also has possible applications in the metallurgy of iron and steel. Its name was derived from _carbon_ and _corundum_ (a form of alumina), from a mistaken view as to its composition. It was first obtained accidentally in 1891 by Acheson in America, when he was experimenting with the electric furnace in the hope of producing artificial diamonds. The experiments were followed up in an incandescence furnace, which on a larger scale is now employed for the industrial manufacture of the product. A full description of the process has been given in the _Journ. Soc. Chem. Industry_, 1897, vol. xvi. p. 863. The furnace is rectangular, a
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