f aniline dyestuffs, and for which it is claimed that they far surpass
logwood, fustic, cudbear, etc., as to fastness against light, and
excellently stand fulling. We allude to the alizarine dyestuffs, which
have long since been introduced and are largely employed in cotton dyeing
and printing.
Alizarine, which has been extensively discussed in various articles in
our journal, is the coloring matter contained in the madder root. In
1869, two German chemists, Graebe and Liebermann, succeeded in
artificially producing this dyestuff from anthracene, a component of
coal-tar. The artificial dyestuff being perfectly pure and free from
those contaminations which render the use of madder difficult, it soon
was preferred to the latter, which it has at present nearly completely
displaced.
The discovery of alizarine red was soon followed by those of alizarine
orange, galleine, coeruleine, and, in 1878, of alizarine blue.
The slow adoption of these dyestuffs in the wool-dyeing industry is
principally attributable to the deep-rooted distrust of wool dyers
against any innovation. This resistance, however, is speedily
disappearing, as every manufacturer and dyer trying the new dyestuffs
invariably finds that they are in no respect inferior to his fastest dyes
produced with indigo and madder, but are simpler to apply and more
advantageous for wool.
The alizarine colors are dyed after an old method which is known to every
wool dyer. The wool is first boiled for 11/2 hours with chromate of potash
and tartar, then dyed upon a fresh bath by 21/2 to 3 hours' boiling. All
alizarine colors (such as those of the Badische Anilin und Soda Fabrik,
of Ludwigshafen and Stuttgart; Wm. Pickhardt & Kuttroff, New York,
Boston, and Philadelphia, viz.):
Alizarine orange W, for brown orange,
Alizarine red WR, for yellow touch ponceau or scarlet,
Alizarine red WB, for blue touch yellow or scarlet,
Alizarine blue WX and SW, for bright blue,
Alizarine blue WR SRW, for dark reddish blue,
Coeruleine W and SW, for green, and
Galleine W, for dahlia,
are dyed after the same method, which offers the great advantage that all
these colors can be dyed upon one bath, and that by their mixture
numerous fast colors can be produced. On the ground of numerous careful
experiments, the writer recommends the following method, which gives well
developed and well fixed colors, viz.:
For 100 kil.--The scoured and washed wool is morda
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