deformation of glass which
manifests itself by the displacement of the zero of a thermometer is
an example. So also the modifications which the phenomena of magnetic
hysteresis or the variations of resistivity have just demonstrated.
Many theorists have taken in hand these difficult questions. M.
Brillouin endeavours to interpret these various phenomena by the
molecular hypothesis. The attempt may seem bold, since these phenomena
are, for the most part, essentially irreversible, and seem,
consequently, not adaptable to mechanics. But M. Brillouin makes a
point of showing that, under certain conditions, irreversible
phenomena may be created between two material points, the actions of
which depend solely on their distance; and he furnishes striking
instances which appear to prove that a great number of irreversible
physical and chemical phenomena may be ascribed to the existence of
states of unstable equilibria.
M. Duhem has approached the problem from another side, and endeavours
to bring it within the range of thermodynamics. Yet ordinary
thermodynamics could not account for experimentally realizable states
of equilibrium in the phenomena of viscosity and friction, since this
science declares them to be impossible. M. Duhem, however, arrives at
the idea that the establishment of the equations of thermodynamics
presupposes, among other hypotheses, one which is entirely arbitrary,
namely: that when the state of the system is given, external actions
capable of maintaining it in that state are determined without
ambiguity, by equations termed conditions of equilibrium of the
system. If we reject this hypothesis, it will then be allowable to
introduce into thermodynamics laws previously excluded, and it will be
possible to construct, as M. Duhem has done, a much more comprehensive
theory.
The ideas of M. Duhem have been illustrated by remarkable experimental
work. M. Marchis, for example, guided by these ideas, has studied the
permanent modifications produced in glass by an oscillation of
temperature. These modifications, which may be called phenomena of the
hysteresis of dilatation, may be followed in very appreciable fashion
by means of a glass thermometer. The general results are quite in
accord with the previsions of M. Duhem. M. Lenoble in researches on
the traction of metallic wires, and M. Chevalier in experiments on the
permanent variations of the electrical resistance of wires of an alloy
of platinum and silv
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