FREE BOOKS

Author's List




PREV.   NEXT  
|<   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125  
126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>   >|  
pposes that metals tend, as it were, to vaporize when in presence of a liquid. A piece of zinc introduced, for example, into pure water gives birth to a few metallic ions. These ions become positively charged, while the metal naturally takes an equal charge, but of contrary sign. Thus the solution and the metal are both electrified; but this sort of vaporization is hindered by electrostatic attraction, and as the charges borne by the ions are considerable, an equilibrium will be established, although the number of ions which enter the solution will be very small. If the liquid, instead of being a solvent like pure water, contains an electrolyte, it already contains metallic ions, the osmotic pressure of which will be opposite to that of the solution. Three cases may then present themselves--either there will be equilibrium, or the electrostatic attraction will oppose itself to the pressure of solution and the metal will be negatively charged, or, finally, the attraction will act in the same direction as the pressure, and the metal will become positively and the solution negatively charged. Developing this idea, Professor Nernst calculates, by means of the action of the osmotic pressures, the variations of energy brought into play and the value of the differences of potential by the contact of the electrodes and electrolytes. He deduces this from the electromotive force of a single battery cell which becomes thus connected with the values of the osmotic pressures, or, if you will, thanks to the relation discovered by Van t' Hoff, with the concentrations. Some particularly interesting electrical phenomena thus become connected with an already very important group, and a new bridge is built which unites two regions long considered foreign to each other. The recent discoveries on the phenomena produced in gases when rendered conductors of electricity almost force upon us, as we shall see, the idea that there exist in these gases electrified centres moving through the field, and this idea gives still greater probability to the analogous theory explaining the mechanism of the conductivity of liquids. It will also be useful, in order to avoid confusion, to restate with precision this notion of electrolytic ions, and to ascertain their magnitude, charge, and velocity. The two classic laws of Faraday will supply us with important information. The first indicates that the quantity of electricity passing through the liquid
PREV.   NEXT  
|<   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125  
126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   >>   >|  



Top keywords:

solution

 
charged
 

attraction

 

liquid

 

osmotic

 

pressure

 
electrostatic
 
electricity
 

important

 
electrified

pressures

 

equilibrium

 

negatively

 

phenomena

 

metallic

 

connected

 

positively

 

charge

 
produced
 

discoveries


relation

 

bridge

 

conductors

 

rendered

 
interesting
 

recent

 
regions
 

concentrations

 

considered

 
discovered

foreign

 

electrical

 

unites

 

centres

 

confusion

 

restate

 
liquids
 

supply

 

Faraday

 

quantity


magnitude

 

velocity

 

classic

 

ascertain

 
electrolytic
 
precision
 

notion

 

conductivity

 
mechanism
 

moving