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When chloride of iron has been produced by sublimation, we may collect it inside a glass bell placed over the fumarole, or upon a piece of brick; but when it is produced by the action of hydrochloric acid on the scoriae, it will only be found on the scoriae themselves. If, therefore, the origin of micaceous peroxide of iron were due to the decomposition of the sesqui-chloride of iron requiring a more elevated temperature for its decomposition, it would follow that its genesis would be easier near the discharging mouths, and more difficult on the lavas, but there the fact was verified: for example, in the great bomb on the fumarole, where we observed micaceous iron transformed into chloride of iron. We may therefore consider it _proved_ that some chlorides--for instance, chloride of sodium--issue from the lava itself, either being there pre-existent, or being formed there; and that others are derived from the oxides which precede them, as undoubtedly is the case with chloride of copper; hence, the theory that derives the oxides always from the chlorides cannot be considered true. Granting that this theory might be applicable to the origin of micaceous iron, we should still want to know how it is found with the paste of the new lava itself, which forms the exterior coating of the bombs above described. Many of these rounded masses, which have been rolled along by the lava, contain scoriae partly decomposed by the long action of the acids found on the fumaroles of the craters. They disintegrate easily, and have a more or less yellowish tint. In the greater number of cases the interior of these masses is formed of leucitic lava, with cavities lined with micaceous iron. In short, their contents appeared to me quite similar to the material of the cone of 1871 and 1872, which in all probability was engulfed in the large crevasse or fissure that opened below it; and the fragments having thus fallen down into the lava, were enveloped by it and carried out by it after having been more or less rounded. The external envelope of these spheres is not at all scoriaceous, but compact and lithoidal, and sometimes composed of concentric folds or plaits. As to the gaseous emanations of fumaroles, watery vapour with few exceptions comes first; this conveys the material which first appears in the sublimations, viz., sea-salt, and for the most part oxide of copper. If the fumarole continue active, it passes from the neutral period to
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