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quite the same as the ashes. But at the beginning of the eruption of the 26th April, a white sand fell in the Atria del Cavallo, close to the Crocella[5], which on the dark scoriae of 1871 looked like snow. Its fall had a limit so well defined that one passed without any gradation from white to black. Having collected some of this sand that very morning, I put it up in white paper, for at that moment it was impossible for me to examine it. Taking it out some days after, I found it had become reddish, and having put it under the microscope, I observed that it was exclusively formed of little pebbles more or less round, of a transparent vitreous matter, partly covered with a red substance. Fragments of green crystals occurred in this sand, upon which no red was perceptible. I consulted our eminent crystallographer, Arcangelo Scacchi, whether these little pebbles were leucite, as I suspected, and whether the green particles were pyroxene: he confirmed my suspicion, and remarked that the red colour was superficial only. We then washed a little of the sand in hot water, and saw the pebbles become whitish; but having heated some on platinum, we observed that they first turned black and then became perfectly white, proving that the red was a deposit of organic matter. To see these leucites, rounded like small pebbles transported by a torrent, deprived of the soluble chlorides which generally accompany Vesuvian ashes, is a matter worthy of attention. Whilst heating this sand upon platinum, decrepitation was audible, which indicated the cracking of some of the little pebbles. It is evident, therefore, that crystals of leucite raised to a certain temperature may break, and thus we can understand how almost all Vesuvian ashes contain fragments of the said crystals enveloped in the paste of the lava. It is evident that the soluble part of the ashes is obtained from the smoke through which it passes. On this occasion the smoke from the craters did not apparently contain much acids, for no bad smell was perceptible, and the water in which I washed the ashes scarcely reddened litmus paper. Even chloride of iron, which was so abundant in the lavas, was scarcely perceptible in the smoke, which almost exclusively deposited sea-salt on the surrounding rocks; I say sea-salt advisedly, and not chloride of sodium, to show that I include all that sea-salt contains. The slight disturbance it manifested with chloride of barium, and the small
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