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that, if it did not always appear as a distinct mineral, it was easily discovered in combination with other chlorides. The specimens which I have collected are not the most beautiful, but the presence of lead in the sublimations is not less common. Micaceous peroxide of iron, when found on the lava, has been mostly conveyed from the eruptive mouths, as I have already stated, and perhaps never so abundantly and evidently as on this occasion. The lava of the 26th of April carried along a large quantity of round masses or bombs, varying in size, among which were found antecedent lava more or less covered with micaceous iron, either collected in the cavities of the lava, or incorporated with its mass. Sometimes the micaceous iron appears like little veins in the paste of new lava enveloping the exterior of these rounded masses, an exterior compact and lithoidal, and not resembling scoriae. Among these spherical masses I found one of enormous size, four to five metres in diameter, which, having broken up where the exterior envelope was thinnest, I found filled with a great mass of lapilli and fragments of other lavas covered with micaceous iron. This bomb still preserves (June 5th) an elevated temperature within, and emits smoke and hydrochloric acid, which, meeting the micaceous iron discovered by breaking the envelope with blows of a hammer, transforms it superficially into chloride of iron, showing most clearly how, on some occasions at least, chloride of iron is formed from the oxide which precedes it. That those lapilli and the pieces of lava were solid when enveloped in the paste of the new lava, we infer from seeing the impressions on the inside of the said envelope. The chloride of calcium, which I found in this spherical mass almost pure, caused me to suspect that the sulphate of lime which is so often found on Vesuvius is a transformation of the chloride produced by the contact of sulphurous acid, which easily becomes transformed into sulphuric acid. The hydrochloric acid which escapes from a fumarole coming into contact with the scoriae near its mouth, produces chloride of iron, which is, therefore, not always obtained by sublimation, although, when the temperature is very high, chloride of iron is conveyed from the interior of the lava, and sublimes on the exterior and colder parts; for instance, the chloride of iron which issues from the eruptive cones is sometimes found sublimed on the rocks of Monte di Somma.
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