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at a loss to conceive how the ether can pass to the state of vapour without an addition of caloric. Does it not contain more caloric in a state of vapour, than in a state of liquidity? MRS. B. It certainly does; for though it is the pressure of the atmosphere which condenses it into a liquid, it is by forcing out the caloric that belongs to it when in an aeriform state. EMILY. You have, therefore, two difficulties to explain, Mrs. B. --First, from whence the ether obtains the caloric necessary to convert it into vapour when it is relieved from the pressure of the atmosphere; and, secondly, what is the reason that the water, in which the bottle of ether stands, is frozen? CAROLINE. Now, I think, I can answer both these questions. The ether obtains the addition of caloric required, from the water in the glass; and the loss of caloric, which the latter sustains, is the occasion of its freezing. MRS. B. You are perfectly right; and if you look at the thermometer which I have placed in the water, whilst I am working the pump, you will see that every time bubbles of vapour are produced, the mercury descends; which proves that the heat of the water diminishes in proportion as the ether boils. EMILY. This I understand now very well; but if the water freezes in consequence of yielding its caloric to the ether, the equilibrium of heat must, in this case, be totally destroyed. Yet you have told us, that the exchange of caloric between two bodies of equal temperature, was always equal; how, then, is it that the water, which was originally of the same temperature as the ether, gives out caloric to it, till the water is frozen, and the ether made to boil? MRS. B. I suspected that you would make these objections; and, in order to remove them, I enclosed two thermometers in the air-pump; one which stands in the glass of water, the other in the phial of ether; and you may see that the equilibrium of temperature is not destroyed; for as the thermometer descends in the water, that in the ether sinks in the same manner; so that both thermometers indicate the same temperature, though one of them is in a boiling, the other in a freezing liquid. EMILY. The ether, then, becomes colder as it boils? This is so contrary to common experience, that I confess it astonishes me exceedingly. CAROLINE. It is, indeed, a most extraordinary circumstance. But pray, how do you account for it? MRS. B. I cannot sati
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