n egg." The theologian
calls it the dogma of natural depravity. The physicist calls it the
second law of thermodynamics. Clausius formulates it as "The entropy of
the world tends toward a maximum." It is easier to smash up than to
build up. Children find that this is true of their toys; the Bolsheviki
have found that it is true of a civilization. So, too, the chemist knows
analysis is easier than synthesis and that creative chemistry is the
highest branch of his art.
This explains why chemists discovered how to take rubber apart over
sixty years before they could find out how to put it together. The first
is easy. Just put some raw rubber into a retort and heat it. If you can
stand the odor you will observe the caoutchouc decomposing and a
benzine-like liquid distilling over. This is called "isoprene." Any
Freshman chemist could write the reaction for this operation. It is
simply
C_{10}H_{16} --> 2C_{5}H_{8}
caoutchouc isoprene
That is, one molecule of the gum splits up into two molecules of the
liquid. It is just as easy to write the reaction in the reverse
directions, as 2 isoprene--> 1 caoutchouc, but nobody could make it go
in that direction. Yet it could be done. It had been done. But the man
who did it did not know how he did it and could not do it again.
Professor Tilden in May, 1892, read a paper before the Birmingham
Philosophical Society in which he said:
I was surprised a few weeks ago at finding the contents of the
bottles containing isoprene from turpentine entirely changed in
appearance. In place of a limpid, colorless liquid the bottles
contained a dense syrup in which were floating several large
masses of a yellowish color. Upon examination this turned out
to be India rubber.
But neither Professor Tilden nor any one else could repeat this
accidental metamorphosis. It was tantalizing, for the world was willing
to pay $2,000,000,000 a year for rubber and the forests of the Amazon
and Congo were failing to meet the demand. A large share of these
millions would have gone to any chemist who could find out how to make
synthetic rubber and make it cheaply enough. With such a reward of fame
and fortune the competition among chemists was intense. It took the form
of an international contest in which England and Germany were neck and
neck.
[Illustration: Courtesy of the "India Rubber World."
What goes into rubber and what is made out of it]
The Eng
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