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rosive used by Rembrandt to bite his plate.[28] Only tentative conclusions can be drawn from this and other prints. The etched lines in the _Landscape with a hay barn_ ... appear to be bitten with a fairly strong acid. The lines are relatively broad in relation to their depth, a strong-acid effect. Furthermore, illustrations of some of Rembrandt's original plates from this period show a similar broad line.[29] In addition, in the photograph (figure 14) of at least one of the plates there is seen a peculiarly ragged line which is often caused by bubbles formed on the plate by acid action.[30] This appearance of bubbles is characteristic only of the strong acids. Of the acid formulae suggested by Bosse in 1645, only one--a distillate of vitriol, saltpeter, and alum--appears to be strong enough to produce the observed effects.[31] Generally speaking, Rembrandt's later etchings show evidence of stronger acid biting than his earlier work, which has more of the characteristics of weak mordants.[32] Certainly, a strong acid would produce a much speedier biting and bolder etched lines, providing him with a solid foundation for his fine drypoint work, and enabling him to work continuously, with a minimum of delay. [Illustration: FIGURE 13 Detail of Rembrandt's finished print, _Landscape with a hay barn and a flock of sheep_, lower right, showing lines of pure etching. Enlarged 10 times. (Smithsonian photo 59387.)] [Illustration: FIGURE 14 Detail of the etched copper plate for Rembrandt's print, _Christ seated disputing with the doctors_. After Coppier, p. 117. (Smithsonian photo 59395.)] [Illustration: FIGURE 15 Detail of Rembrandt's finished print, _Landscape with a hay barn and a flock of sheep_, far right, showing drypoint drawing of sheep and post. Enlarged 10 times. (Smithsonian photo 59388.)] Rembrandt's use of drypoint is, as Jakob Rosenberg says, "the most important innovation in Rembrandt's mature graphic work."[33] After etching his skeletal design on the plate, he went to work with his drypoint needles--long, stiff, iron instruments--sharpened to a fine point. An artist generally has several available, so that he does not have to stop and re-sharpen in the course of his work. Rembrandt evidently went even further and deliberately used dull needles to obtain certain light line effects. When the finished print is compared with the sketch of the etched lines alone, it can be seen how vital the drypoint
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