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============+============== | | APPROXIMATE | PERCENTAGE OF | PART OF | DENSITY BY | MOLECULAR | NITROGEN BY | MOLECULAR | EXPERIMENT | WEIGHT | EXPERIMENT | WEIGHT DUE | | (D. x 28.9) | | TO NITROGEN ------------------+------------+-------------+----------------+-------------- Nitrogen gas | 0.9671 | 27.95 | 100.00 | 27.95 Nitrous oxide | 1.527 | 44.13 | 63.70 | 27.11 Nitric oxide | 1.0384 | 30.00 | 46.74 | 14.02 Nitrogen peroxide | 1.580 | 45.66 | 30.49 | 13.90 Ammonia | 0.591 | 17.05 | 82.28 | 14.03 Nitric acid | 2.180 | 63.06 | 22.27 | 14.03 Hydrocyanic acid | 0.930 | 26.87 | 51.90 | 13.94 ==================+============+=============+================+============== ~Method of calculation.~ The densities of the various gases in the first column of this table are determined by experiment, and are fairly accurate but not entirely so. By multiplying these densities by 28.9 the molecular weights of the compounds as given in the second column are obtained. By chemical analysis it is possible to determine the percentage composition of these substances, and the percentages of nitrogen in them as determined by analysis are given in the third column. If each of these molecular weights is multiplied in turn by the percentage of nitrogen in the compound, the product will be the weight of the nitrogen in the molecular weight of the compound. This will be the sum of the weights of the nitrogen atoms in the molecule. These values are given in the fourth column in the table. If a large number of compounds containing nitrogen are studied in this way, it is probable that there will be included in the list at least one substance whose molecule contains a single nitrogen atom. In this case the number in the fourth column will be the approximate atomic weight of nitrogen. On comparing the values for nitrogen in the table it will be seen that a number which is approximately 14 is the smallest, and that the others are multiples of this. These compounds of higher value, therefore, contain more than one nitrogen atom in the molecule. ~Accurate determination of atomic weights.~ Molecular weights cannot be determined very
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