FREE BOOKS

Author's List




PREV.   NEXT  
|<   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72  
73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   >>   >|  
magnificent blue was the final result. But here also the dye was of a basic character, and being insoluble in water had only a limited application, as a spirit bath had to be used for dissolving the substance. In 1862, however, an English technologist, the late E. C. Nicholson, found that by the action of strong sulphuric acid the aniline blue could be rendered soluble in water or alkali, and the value of the colouring-matter was enormously increased by this discovery. The basic and slightly soluble spirit blue was by this means converted into acid blues, which are now made in large quantities, and sold under the names of Nicholson's blue, alkali blue, soluble blue, and other trade designations. There is at the present time hardly any other blue which for fastness, facility of dyeing, and beauty can compete with this colouring-matter introduced by Nicholson as the outcome of the work of Girard and De Laire. Other transformations of rosaniline have yet to be chronicled. In 1862 Hofmann found that by acting upon this base--the base of magenta--with the iodide of methyl, violet colouring-matters were produced, and these were for some years extensively employed under the name of Hofmann's violets. And still more remarkable, by the prolonged action of an excess of methyl iodide upon rosaniline, Keisser found that a green colouring-matter was formed. The latter was patented in 1866, and the dye was for some time in use under the name of "iodine green." The statement that technology profited by the introduction of magenta has therefore been justified. It remains to add, that the tar obtained from one ton of Lancashire coal furnishes an amount of aniline capable of giving a little over half a pound of magenta. The colouring power of the latter will be inferred from the fact, that this quantity would dye 375 square yards of white flannel of a full red colour, and if converted into Hofmann violet by methylation, would give enough colour to dye double this surface of flannel of a deep violet shade. It should be stated also, that during the formation of magenta by the arsenic acid process, there are formed small quantities of other colouring-matters which are utilized by the manufacturer. Among these by-products is a basic orange dye, which was isolated by Nicholson, and investigated by Hofmann in 1862. Under the name of "phosphine" this colouring-matter is still used, especially for the dyeing of leather. Even the spent arsenic
PREV.   NEXT  
|<   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72  
73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   >>   >|  



Top keywords:

colouring

 

Hofmann

 
matter
 
Nicholson
 

magenta

 

soluble

 
violet
 

formed

 

flannel

 
converted

colour
 

quantities

 

matters

 

methyl

 

rosaniline

 

iodide

 

dyeing

 

action

 

spirit

 

arsenic


aniline

 
alkali
 
orange
 

obtained

 

utilized

 
isolated
 

products

 

investigated

 

manufacturer

 
remains

iodine
 
statement
 

leather

 
technology
 

phosphine

 

profited

 
introduction
 

justified

 

amount

 

square


stated

 

patented

 
methylation
 

double

 

surface

 

formation

 

quantity

 
capable
 

giving

 

furnishes