FREE BOOKS

Author's List




PREV.   NEXT  
|<   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66  
67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   >>   >|  
h air, it produces the most annoying irritation of the throat, with stricture of the chest and a severe cough, which continues for hours, with the discharge of much thick mucus. The attempt to breathe the undiluted gas would be fatal; yet, in a very small quantity, and dissolved in water, it is used with benefit by patients suffering under pulmonary consumption. Under a pressure of about four atmospheres, it becomes a limpid fluid of a fine yellow color, which does not freeze at zero, and is not a conductor of electricity. It immediately returns to the gaseous state with effervescence on removing the pressure. Water recently boiled will absorb, if cold, about twice its bulk of chlorine gas, acquiring its color and characteristic properties. The moist gas, exposed to a cold of 32 deg., yields beautiful yellow crystals, which are a definite compound of one equivalent of chlorine and ten of water. If these crystals are hermetically sealed up in a glass tube, they will, on melting, exert such a pressure as to liquefy a portion of the gas, which is distinctly seen as a yellow fluid, not miscible with the water which is present. Chlorine is one of the heaviest of the gases, its density being 2.47, and 100 cubic inches weighing 76.5 grains. Chlorine Water.--This combination, which is used in conducting M. Neipce's process, can be readily prepared by conducting the gas into a bottle containing distilled water. One part water dissolves two parts of chlorine. Chlorides.--The metallic chlorides are nearly all soluble in water; that of silver and protochloride of mercury being the only exceptions. A metallic chloride, treated with oil of vitriol, disengages chlorohydric acid. Heated with a mixture of peroxide of manganese and sulphuric acid, chlorine is given off, which is easily recognized by its odor and other physical properties. The chlorides dissolve in water; give with nitrate of silver, a white precipitate, even in highly diluted solutions, becoming violet colored and finally black when exposed to the light. The rapidity of the change of color is proportioned to the intensity of the light. It is insoluble in nitric acid, but readily soluble in ammonia; it fuses without decomposition, forming, when cold, a tough, horny mass, and is reduced by hydrogen and by fusion with carbonate of soda, or with resin. Chloride of Bromine. (See page 74.) Chloride of Iodine. (See page 85.) Chloride of potassium.--
PREV.   NEXT  
|<   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66  
67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   >>   >|  



Top keywords:

chlorine

 
pressure
 
Chloride
 

yellow

 
silver
 
soluble
 
chlorides
 

metallic

 

crystals

 

exposed


Chlorine
 
readily
 

conducting

 
properties
 
disengages
 

physical

 
chlorohydric
 

irritation

 

vitriol

 

exceptions


chloride

 

treated

 

Heated

 

mixture

 

easily

 

recognized

 

sulphuric

 
peroxide
 
manganese
 

protochloride


distilled

 

bottle

 
process
 

prepared

 

dissolves

 

stricture

 

throat

 

dissolve

 

Chlorides

 
severe

mercury

 

nitrate

 

reduced

 

hydrogen

 
fusion
 

carbonate

 

decomposition

 

forming

 

Iodine

 

potassium