FREE BOOKS

Author's List




PREV.   NEXT  
|<   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88  
89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   >>  
the deposit ranges from 94 to 94.76 per cent. The peroxide precipitated from a nitric solution may, under certain circumstances, be anhydrous. This result is due to the secondary influences at the positive pole, where the free acid gradually withdraws water from the peroxide. The peroxide thrown down from alkaline solutions retains alkali so obstinately that it cannot be removed by washing; the peroxide plays here the part of an acid. The lead nitrate mechanically inclosed in the peroxide is resolved by ignition into oxide, hyponitric acid, and oxygen; this small proportion of lead oxide does not exert an important influence on the final result. The quantity of matter mechanically inclosed is relatively high, as in the precipitation of much lead peroxide there is relatively more saline matter occluded than when a few centigrammes are deposited. The peroxide incloses also more foreign matter if it is thrown down upon a small surface than if it is deposited in a thin layer over a broad surface. From numerous analyses the author concludes that in presence of much free nitric acid the proportion of water is increased; with free alkali the reverse holds good. _Thallium_ behaves similarly to lead. From a nitric acid solution it is thrown down, according to the proportion of free acid, either as sesquioxide only or in small quantities as silvery, metallic leaflets; from alkaline solutions it is deposited as sesquioxide and metal, the latter of a lead-gray color. Thallium solutions conduct the electric current badly. Thallium oxide resembles lead peroxide in color; at a strong heat it melts, becomes darker, and is converted into peroxide, in which state it can be weighed. _Silver._--All solutions of silver salts, except the nitrate, and those containing a very large quantity of free nitric acid or nitrates, deposit electrolytically merely metallic silver. In the above mentioned exceptional cases there is formed a small quantity of peroxide which adheres to the anode as a blackish-gray deposit. The greatest quantity of peroxide is obtained on employing a concentrated, strongly acid solution of the nitrate, and a strong current. If the solution is very dilute we obtain no peroxide, or mere traces which disappear again toward the end of the process. The peroxide is deposited at first in small, dark, shining octahedral crystals; subsequently, in an amorphous state. At 110 deg. it evolves oxygen suddenly, and is converted in
PREV.   NEXT  
|<   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88  
89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   >>  



Top keywords:

peroxide

 
solutions
 
deposited
 

quantity

 
nitric
 
solution
 
nitrate
 

matter

 

deposit

 

Thallium


proportion
 

thrown

 

mechanically

 

surface

 
oxygen
 
metallic
 

silver

 

inclosed

 

sesquioxide

 
strong

current
 

result

 

alkaline

 

converted

 
alkali
 

electric

 

leaflets

 
conduct
 

nitrates

 
resembles

darker
 

Silver

 

weighed

 

greatest

 

process

 
traces
 

disappear

 

shining

 

octahedral

 
evolves

suddenly

 

crystals

 

subsequently

 

amorphous

 
formed
 

adheres

 

exceptional

 
mentioned
 

blackish

 

dilute