FREE BOOKS

Author's List




PREV.   NEXT  
|<   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98  
99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   >>  
it on evaporation in a crystalline form. _General Reactions for Alkaloids._--(1) Wagner's reagent (iodine dissolved in a solution of potassium iodide) yields a reddish-brown precipitate; (2) Mayer's reagent (potassio-mercuric iodide) gives a yellowish-white precipitate; (3) phospho-molybdic acid gives a yellow precipitate; (4) platinic chloride, a brown precipitate; (5) tannic acid, etc. In order to isolate an inorganic substance from organic matter, Fresenius's method is adopted. Boil the finely divided substance with about one-eighth its bulk of pure hydrochloric acid; add from time to time potassic chlorate until the solids are reduced to a straw-yellow fluid. Treat this with excess of bisulphate of sodium, then saturate with sulphuretted hydrogen until metals are thrown down as sulphides. These may be collected and tested. From the acid solution, hydrogen sulphide precipitates copper, lead, and mercury, _dark_; arsenic, antimony, and tin, _yellowish_. If no precipitate, add ammonia and ammonium sulphide, iron, _black_, zinc, _white_, chromium, _green_, manganese, _pink_. The residue of the material after digestion with hydrochloric acid and potassium chlorate may have to be examined for silver, lead, and barium. For the detection of minute quantities, the microscope must be used, and Guy's and Helwig's method of sublimation will be found advantageous. Crystalline poisons may be recognized by their characteristic forms. IX.--THE MINERAL ACIDS These are sulphuric, nitric, and hydrochloric acids. _Symptoms of Poisoning by the Mineral Acids._--Acid taste in the mouth, with violent burning pain extending into the oesophagus and stomach, and commencing immediately on the poison being swallowed; eructations, constant retching, and vomiting of brown, black, or yellow matter containing blood, coagulated mucus, epithelium, or portions of the lining membrane of the gullet and stomach. The vomited matters are strongly acid in reaction, and stain articles of clothing on which they may fall. There is intense thirst and constipation, with scanty or suppressed urine, tenesmus, and small and frequent pulse; the lips, tongue, and inside of the mouth, are shrivelled and corroded. Exhaustion succeeds, and the patient dies either collapsed, convulsed, or suffocated, the intellect remaining clear to the last. After recovering from the acute form of poisoning, the patient may ultimately die from starvation, due to st
PREV.   NEXT  
|<   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98  
99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   >>  



Top keywords:

precipitate

 

yellow

 

hydrochloric

 

substance

 
patient
 
matter
 

method

 

sulphide

 

chlorate

 

solution


yellowish

 

reagent

 

hydrogen

 

potassium

 

stomach

 

iodide

 

vomiting

 
commencing
 

poison

 

swallowed


eructations
 
constant
 

immediately

 

retching

 

characteristic

 

MINERAL

 

recognized

 
advantageous
 

Crystalline

 

poisons


sulphuric

 
nitric
 

burning

 
violent
 

extending

 

coagulated

 
Symptoms
 
Poisoning
 

Mineral

 

oesophagus


articles

 

collapsed

 

convulsed

 

suffocated

 

succeeds

 

Exhaustion

 
tongue
 

inside

 
shrivelled
 

corroded