FREE BOOKS

Author's List




PREV.   NEXT  
|<   6   7   8   9   10   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30  
31   32   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   >>   >|  
es are fused with others more fusible (reagents) for the purpose of causing a combination which is soluble in water and acids, the operation is termed _unclosing_. These substances are particularly the silicates and the sulphates of the alkaline earths. The usual reagents resorted to for this purpose are carbonate of soda (NaO, CO^{2}), carbonate of potash (KO, CO^{2}), or still better, a mixture of the two in equal parts. In some cases we use the hydrate of barytes (BaO, HO) and the bisulphate of potash (KO, 2SO^{3}). The platinum spoon is generally used for this manipulation. Substances are exposed to fusion for the purpose of getting a new combination which has such distinctive characteristics that we can class it under a certain group; or for the purpose of ascertaining at once what the substance may be. The reagents used for this purpose are borax (NaO, 2BrO^{3}) and the microcosmic salt (NaO, NH^{4}O, PO^{5}, HO). Charcoal and the platinum wire are used as supports for this kind of operation. (_d._) _Oxidation._--The chemical combination of any substance with oxygen is termed _oxidation_, and the products are termed _oxides_. As these oxides have qualities differing from those which are non-oxidized, it therefore frequently becomes necessary to convert substances into oxides; or, if they are such, of a lower degree, to convert them into a higher degree of oxidation. These different states of oxidation frequently present characteristic marks of identity sufficient to enable us to draw conclusions in relation to the substance under examination. For instance, the oxidation of manganese, of arsenic, etc. The conditions necessary for oxidation, are high temperature and the free admission of air to the substance. If the oxidation is effected through the addition of a substance containing oxygen (for instance, the nitrate or chlorate of potash) and the heating is accompanied by a lively deflagration and crackling noise, it is termed _detonation_. By this process we frequently effect the oxidation of a substance, and thus we prove the presence or the absence of a certain class of substances. For instance, if we detonate (as it is termed by the German chemists) the sulphide of antimony, or the sulphide of arsenic with nitrate of potash, we get the nitrate of antimony, or the nitrate of arsenic. The salts of nitric or chloric acid are determined by fusing them with the cyanide of potassium, because the salts of thes
PREV.   NEXT  
|<   6   7   8   9   10   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30  
31   32   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   >>   >|  



Top keywords:
oxidation
 

substance

 

termed

 

purpose

 

nitrate

 
potash
 
oxides
 

reagents

 

arsenic

 

substances


combination

 
instance
 

frequently

 

platinum

 

carbonate

 

convert

 

antimony

 

sulphide

 

oxygen

 

operation


degree
 

examination

 

relation

 
manganese
 
higher
 
oxidized
 
enable
 

identity

 

sufficient

 

conclusions


states

 
present
 

characteristic

 

accompanied

 

absence

 
detonate
 

German

 

chemists

 

presence

 
process

effect

 

nitric

 

potassium

 
cyanide
 

fusing

 

chloric

 

determined

 

detonation

 

effected

 
admission