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to diffusion would be analogous to friction, and would contain terms which were independent of the relative velocity u2 - u1. (2) For slow motions the resistance to diffusion is (approximately at any rate) proportional to the relative velocity. (3) The coefficient of resistance C is not necessarily always constant; it may, for example, and, in general, does, depend on the temperature. If we form the equations of hydrodynamics for the different fluids occurring in any mixture, taking account of diffusion, but neglecting viscosity, and using suffixes 1, 2 to denote the separate fluids, these assume the form given by James Clerk Maxwell ("Diffusion," in _Ency. Brit._, 9th ed.):-- Du1 dp1 [rho] --- + --- - X1[rho]1 + C12[rho]1[rho]2(u1 - u2) + &c. = 0, Dt dx where Du1 du1 du1 du1 du1 --- = --- + u1 --- + v1 --- + w1 ---, Dt dt dx dy dz and these equations imply that when diffusion and other motions cease, the fluids satisfy the separate conditions of equilibrium dp1/dx - X1[rho]1 = 0. The assumption made in the following account is that terms such as Du1/Dt may be neglected in the cases considered. A further property based on experience is that the motions set up in a mixture by diffusion are very slow compared with those set up by mechanical actions, such as differences of pressure. Thus, if two gases at equal temperature and pressure be allowed to mix by diffusion, the heavier gas being below the lighter, the process will take a long time; on the other hand, if two gases, or parts of the same gas, at different pressures be connected, equalization of pressure will take place almost immediately. It follows from this property that the forces required to overcome the "inertia" of the fluids in the motions due to diffusion are quite imperceptible. At any stage of the process, therefore, any one of the diffusing fluids may be regarded as in equilibrium under the action of its own partial pressure, the external forces to which it is subjected and the resistance to diffusion of the other fluids. 5. _Slow Diffusion of two Gases. Relation between the Coefficients of Resistance and of Diffusion._--We now suppose the diffusing substances to be two gases which obey Boyle's law, and that diffusion takes place in a closed cylinder or tube of unit sectional area at constant temperature, the surfaces of equal density being p
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