one
solid, and one liquid. The lower the temperature is kept, the more of
the solid body is produced. To obtain the solid body pure it is
pressed and recrystallized from ether or alcohol. It is volatile and
has the odor of camphor. It is called artificial camphor, and has the
composition C10 H16 HCl. There is also a compound with 2HCl.
Oxidation products. By passing air into spirits of turpentine oxygen
is absorbed. It was thought at one time that ozone was produced, but
Kingzett's view is that camphoric peroxide is formed C10 H14 O4,
and that in presence of water it decomposes into camphoric acid and
H2 O2. This liquid constitutes the disinfectant known as
"sanitas," which possesses the advantages of a pleasant smell and
non-poisonous properties. C10 H18 O2 may be obtained by
exposing spirits of turpentine in a flask full of oxygen with a little
water.
Camphor C16 H16 O has been made in small quantity by oxidizing spirits
of turpentine. Terebenthene belongs to the benzene or aromatic series,
which can be shown from its connection with cymene. Cymene is
methylpropyl-benzene, and can be made from terpenes by removing two
atoms of H. It has not yet been converted again into terpene, but the
connection is sufficiently proved. The presence of CH3 in terpenes is
shown by their yielding chloroform when distilled with bleaching
powder and water. The resin is imperfectly known. It was supposed to
consist of picric and sylvic acids. It is also stated to contain
abietic anhydride C44 H62 O4, but it is difficult to understand how a
compound containing C44 can be produced from C10 H16. The most
probable view is that it is the anhydride of sylvic acid, which is
probably C20 H30 O2.
The dark colored resin which is obtained when the turpentine is
distilled without water can be converted into a transparent slightly
yellow body by distillation with superheated steam. A small portion is
decomposed, but the greater part distills unchanged. It is used in
making soap which will lather with sea water.
When distilled alone, various hydrocarbons, resin oil and resin pitch,
are obtained.
I find that commercial spirits of turpentine varies in sp. gr. from
0.865 to 0.869 at 15 deg. C. The higher sp. gr. appears to be connected
with the presence of resinous bodies, the result of oxidation. The
boiling point is very uniform, ranging from 155 deg. C. to 157 deg. C. at 760
mm. Taking these two points together, it is hardly possible to
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