FREE BOOKS

Author's List




PREV.   NEXT  
|<   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63  
64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   >>   >|  
nto organic compounds, hydrogen can link itself with only a single bond to any other element--it has, so to speak, but a single hand with which to grasp--while oxygen has capacity for two bonds, nitrogen for three (possibly for five), and carbon for four. The words monovalent, divalent, trivalent, tretrava-lent, etc., were coined to express this most important fact, and the various elements came to be known as monads, diads, triads, etc. Just why different elements should differ thus in valency no one as yet knows; it is an empirical fact that they do. And once the nature of any element has been determined as regards its valency, a most important insight into the possible behavior of that element has been secured. Thus a consideration of the fact that hydrogen is monovalent, while oxygen is divalent, makes it plain that we must expect to find no more than three compounds of these two elements--namely, H--O--(written HO by the chemist, and called hydroxyl); H--O--H (H2O, or water), and H--O--O--H (H2O2, or hydrogen peroxide). It will be observed that in the first of these compounds the atom of oxygen stands, so to speak, with one of its hands free, eagerly reaching out, therefore, for another companion, and hence, in the language of chemistry, forming an unstable compound. Again, in the third compound, though all hands are clasped, yet one pair links oxygen with oxygen; and this also must be an unstable union, since the avidity of an atom for its own kind is relatively weak. Thus the well-known properties of hydrogen peroxide are explained, its easy decomposition, and the eagerness with which it seizes upon the elements of other compounds. But the molecule of water, on the other hand, has its atoms arranged in a state of stable equilibrium, all their affinities being satisfied. Each hydrogen atom has satisfied its own affinity by clutching the oxygen atom; and the oxygen atom has both its bonds satisfied by clutching back at the two hydrogen atoms. Therefore the trio, linked in this close bond, have no tendency to reach out for any other companion, nor, indeed, any power to hold another should it thrust itself upon them. They form a "stable" compound, which under all ordinary circumstances will retain its identity as a molecule of water, even though the physical mass of which it is a part changes its condition from a solid to a gas from ice to vapor. But a consideration of this condition of stable equilibrium in the
PREV.   NEXT  
|<   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63  
64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   >>   >|  



Top keywords:

oxygen

 

hydrogen

 

elements

 

compounds

 
compound
 

stable

 

element

 

satisfied

 

peroxide

 

clutching


consideration

 

equilibrium

 

valency

 
condition
 
monovalent
 
divalent
 

companion

 

unstable

 

molecule

 

important


single

 

seizes

 

eagerness

 
clasped
 

avidity

 

properties

 
explained
 
decomposition
 

Therefore

 
ordinary

circumstances
 

retain

 
thrust
 

identity

 
physical
 

affinity

 

affinities

 
arranged
 

tendency

 

linked


monads

 
triads
 

coined

 

express

 
empirical
 

differ

 

tretrava

 

organic

 
capacity
 

nitrogen