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se of Sir Humphry Davy to the highest rank as a chemical philosopher, was, after his appointment at the Royal Institution, rapid and brilliant; and if he was previously aided by as few of the advantages of fortune as any man living, he had then at his disposal whatever his industry and talents chose to command. We have given but a hasty outline of his labours; but it is possible that he may have left behind him much, not yet made public, for which, science will be still further indebted to him. His works, papers, and letters are numerous, and the greatest portion of them are contained in the Transactions of the Royal Society. One of the most popular and interesting of his recent papers is that on the _Phenomena of Volcanoes_. This contains a series of investigations of Vesuvius, made by the author during a residence at Naples in 1819-20, and bearing upon a previous hypothesis, "that metals of the alkalies and earth might exist in the interior of the globe, and on being exposed to the action of air and water, give rise to volcanic fires, and to the production of lavas, by the slow cooling of which basaltic and other crystalline rocks might subsequently be formed." We have not space for the details of these investigations, interesting as they would prove to an unscientific reader; but we give an abstract of the result of Sir Humphry's observations: "The phenomena observed by the author afforded a sufficient refutation of all the ancient hypotheses, in which volcanic fires were ascribed to such chemical causes as the combustion of mineral coal, or the action of sulphur upon iron; and are perfectly consistent with the supposition of their depending upon the oxidation of the metals of the earths upon an extensive scale, in immense subterranean cavities, to which water or atmospheric air may occasionally have access. The subterranean thunder heard at great distances under Vesuvius, prior to an eruption, indicates the vast extent of these cavities; and the existence of a subterranean communication between the Solfattara and Vesuvius, is established by the fact that whenever the latter is in an active state, the former is comparatively tranquil. In confirmation of these views, the author remarks, that almost all the volcanoes of considerable magnitude in the old world, are in the vicinity of the sea; and in those where the sea is more distant, as in the volcanoes of South America, the water may be supplied from great subterrane
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