FREE BOOKS

Author's List




PREV.   NEXT  
|<   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88  
89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   >>   >|  
alysis as elaborated and employed by Dr. Fisher and the author, is as follows: I. To prepare a sample for analysis, half a pound, more or less, of the substance is pulverized and passed through a wire sieve of 24 meshes to the inch. It is then thoroughly mixed and bottled. II. 2 grammes of the above are dried (in tared watch-glasses) at the temperature of 212 degrees, until they no longer decrease in weight. The loss sustained represents the _amount of water_, (according to MARSILLY, Annales des Mines, 1857, XII., 404, peat loses carbon if dried at a temperature higher than 212 degrees.) III. The capsule containing the residue from I. is slowly heated to incipient redness, and maintained at that temperature until the organic matter is entirely consumed. The loss gives the total amount of _organic_, the residue the total amount of _inorganic_ matter. NOTE.--In peats containing sulphate of the protoxide of iron, the loss that occurs during ignition is partly due to the escape of sulphuric acid, which is set free by the decomposition of the above mentioned salt of iron. But the quantity is usually so small in comparison with the organic matter, that it may be disregarded. The same may be said of the combined water in the clay that is mixed with some mucks, which is only expelled at a high temperature. IV. 3 grammes of the sample are digested for half an hour, with 200 cubic centimeters (66.6 times their weight,) of boiling water, then removed from the sand bath, and at the end of twenty-four hours, the clear liquid is decanted. This operation is twice repeated upon the residue; the three solutions are mixed, filtered, concentrated, and finally evaporated to dryness (in a tared platinum capsule,) over a water bath. The residue, which must be dried at 212 degrees, until it ceases to lose weight, gives the _total amount soluble in water_. The dried residue is then heated to low redness, and maintained at that temperature until the organic matter is burned off. The loss represents the amount of _organic matter soluble in water_, the ash gives the quantity of _soluble inorganic matter_. V. 1 gramme is digested for two hours, at a temperature just below the boiling point, with 100 cubic centimeters of a solution containing 5 _per cent._ of crystallized carbonate of soda. It is then removed from the sand bath and allowed to settle. When the supernatant liquid has become perfectly transparent, it is carefully decanted.
PREV.   NEXT  
|<   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88  
89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   >>   >|  



Top keywords:
temperature
 

matter

 

organic

 
residue
 

amount

 

soluble

 

degrees

 

weight

 

decanted

 

maintained


boiling

 
centimeters
 

quantity

 
digested
 
removed
 

capsule

 

heated

 

redness

 

inorganic

 

liquid


represents

 

grammes

 

sample

 

supernatant

 

allowed

 
settle
 

crystallized

 

carbonate

 

combined

 

perfectly


transparent

 

carefully

 
twenty
 

expelled

 

finally

 

evaporated

 

dryness

 

concentrated

 

filtered

 

solutions


ceases
 
burned
 

platinum

 

repeated

 

solution

 
operation
 

gramme

 
protoxide
 
bottled
 

meshes