FREE BOOKS

Author's List




PREV.   NEXT  
|<   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68  
69   70   71   72   73   74   75   76   77   78   >>  
btained. When metals in liquids are heated, they are more frequently rendered positive than negative in the proportion of about 2.8 to 1.0; and while the proportion in weak solutions was about 2.29 to 1.0, in strong ones it was about 3.27 to 1.0, and this accords with their thermo-electric behavior as metals alone. The thermo-electric order of metals in liquids was, with nearly every solution, whether strong or weak, widely different from the thermo-electric order of the same metals alone. A conclusion previously arrived at was also confirmed, viz., that the liquids in which the hot metal was thermo-electro-positive in the largest proportion of cases were those containing highly electro-positive bases, such as the alkali metals. The thermo-electric effect of _gradually_ heating a metal in a liquid was sometimes different from that of _suddenly_ heating it, and was occasionally attended by a reversal of the current. Degree of strength of liquid greatly affected the thermo-electric order of metals. Increase of strength usually and considerably increased the potential of metals thermo-electro-negative in liquids, and somewhat increased that of those positive in liquids. The electric potential of metals, thermo-electro-positive in weak liquids, was usually about 3.87 times, and in strong ones 1.87 times, as great as of those which were negative. The potential of the strongest thermo-electric couple, viz., that of aluminum in weak solution of sodic phosphate, was 0.66 volt for 100 deg. F. difference of temperature, or about 100 times that of a bismuth and antimony couple. Heating one of the metals, either the positive or negative, of a voltaic couple, usually increased their electric difference, making most metals more positive, and some more negative; while heating the second one also usually neutralized to a large extent the effect of heating the first one. The electrical effect of heating a voltaic couple is nearly wholly composed of the united effects of heating each of the two metals separately, but is not however exactly the same, because while in the former case the metals are dissimilar, and are heated to the same temperature, in the latter they are similar, but heated to different temperatures. Also, when heating a voltaic pair, the heat is applied to two metals, both of which are previously electro-polar by contact with each other as well as by contact with the liquid; but when heating one junction of a met
PREV.   NEXT  
|<   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68  
69   70   71   72   73   74   75   76   77   78   >>  



Top keywords:

metals

 

thermo

 
electric
 
heating
 
positive
 

liquids

 

negative

 

electro

 

couple

 

liquid


effect

 

increased

 

heated

 

proportion

 

strong

 
voltaic
 

potential

 
strength
 

difference

 
temperature

contact

 

previously

 
solution
 

neutralized

 

making

 

junction

 

bismuth

 

antimony

 

Heating

 

electrical


temperatures

 
similar
 

separately

 

wholly

 

dissimilar

 

applied

 

composed

 

effects

 

united

 

extent


attended

 

arrived

 

conclusion

 

widely

 

confirmed

 

highly

 
largest
 
solutions
 
rendered
 

behavior