FREE BOOKS

Author's List




PREV.   NEXT  
|<   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   >>  
om the fibrous, and forms a denser mass. The softer kinds of the granular gypsum are those principally used in the production of plaster for the moulds of potteries. In the old fashioned process which is still employed for making the common kinds of plaster, the material is exposed to the direct action of flame. Large lumps are placed in the lower part of the furnace, above them smaller lumps, and, after the heating has been carried on for some time, finely divided material is filled in at the top. The outer portion of the larger lumps is always overburnt, and in the upper part of the furnace the presence of shining crystalline particles generally indicates the fact that some gypsum has remained unchanged. Provided that the amount of unburnt and overburnt material does not exceed about 30 per cent. of the total, the plaster is suitable for many applications. It was early observed that set plaster could be revivified by a second baking, but attempts in this direction were not uniformly successful, it being found that the dehydrated substance in some cases refused to set with water. It behaved in fact similarly to the natural anhydrous calcium sulphate which is unaffected by water. These failures were found to be due to the employment of too high a temperature, and such plaster was termed _dead burnt_. Although this fact was ascertained long ago, yet ignorance of what had already been done has probably been the cause of many disappointments in attempts at revivification which have been made from time to time by persons unacquainted with the history of the subject. The view generally adopted with regard to the theory of these processes is that plaster consists of anhydrous calcium sulphate, CaSO4, in a condition probably amorphous, different from that of natural crystallized CaSO4, known to mineralogists under the name of anhydrite. By the influence of a high temperature it appears probable that a molecular change is gradually induced with production of a crystalline structure, and probably an increase of specific gravity, resulting in the artificial reproduction of the mineral anhydrite. No determination appears to have been published of the specific gravity of plaster prepared by complete baking at a low temperature. The theory is, however, confirmed by the results obtained by workers on the subject of mineralogical synthesis, who have shown that the material which has been produced at high temperatures has the sp
PREV.   NEXT  
|<   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   >>  



Top keywords:

plaster

 

material

 

temperature

 

appears

 

baking

 

furnace

 

subject

 

crystalline

 

generally

 
theory

overburnt
 

anhydrite

 

specific

 
gypsum
 

anhydrous

 

attempts

 
natural
 

production

 
calcium
 

gravity


sulphate
 

history

 

unacquainted

 

persons

 

termed

 

ignorance

 

disappointments

 

Although

 

ascertained

 

revivification


mineralogists

 

published

 

prepared

 
complete
 

determination

 

resulting

 

artificial

 
reproduction
 

mineral

 
confirmed

produced
 
temperatures
 

synthesis

 

results

 

obtained

 

workers

 

mineralogical

 

increase

 
amorphous
 

crystallized