FREE BOOKS

Author's List




PREV.   NEXT  
|<   9   10   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33  
34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   >>   >|  
re I never heard that any of the factory hands suffered, nor did I suffer, from arsenical poisoning. If there is any abrasion of the skin the dust produces a sore, and also the delicate lining of the nostrils is apt to be affected. It is in this way it acts in large doses; I am therefore very skeptical as to its supposed poisonous effects when wall-paper is stained with it. Different methods are given in works on chemistry for the manufacture of this pigment, but as they do not agree in every respect with the method which was followed in English color factories some years ago, it will be as well, for the full elucidation of the manufacture of this substance, to briefly recite some of these methods before describing the one that was, and probably is still, in use; and I will afterward describe a method which I invented, and which is practically superior to any other, both in the rapidity with which the color can be formed, and for producing it at a less cost. It is stated in Watts' "Dictionary of Chemistry" that it is "prepared on a large scale by mixing arsenious acid with cupric acetate and water. Five parts of verdigris are made up to a thin paste, and added to a boiling solution of 4 parts or rather more of arsenious acid in 50 parts of water. The boiling must be well kept up, otherwise the precipitate assumes a yellow-green color, from the formation of copper arsenite; in that case acetic acid must be added, and the boiling continued a few minutes longer. The precipitate then becomes crystalline, and acquires the fine green color peculiar to the aceto-arsenite." I do not know from personal knowledge, but I have always understood that the copper salt employed in its manufacture in France is the acetate. This would account, in my opinion, for the larger crystalline flakes in which it is obtained in France than can be produced by the English method of manufacturing it. Cupric acetate is never employed, I believe, in England--the much cheaper copper salt, the sulphate, being always employed. In "Miller's Chemistry" it is stated it "may be obtained by _boiling_ solutions of arsenious anhydride and cupric acetate, and adding to the mixture an equal bulk of _cold_ water." Why it should be recommended to add _cold water_, I am at a loss to understand. In Drs. Roscoe and Schorlemmer's large work on "Chemistry," and in the English edition of "Wagner's Handbook of Chemical Technology," edited by Mr. Crookes, the process
PREV.   NEXT  
|<   9   10   11   12   13   14   15   16   17   18   19   20   21   22   23   24   25   26   27   28   29   30   31   32   33  
34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57   58   >>   >|  



Top keywords:

boiling

 

acetate

 

employed

 

arsenious

 

English

 

manufacture

 
method
 

Chemistry

 

copper

 
arsenite

France

 

crystalline

 

precipitate

 

obtained

 
cupric
 

stated

 
methods
 

understood

 

personal

 

knowledge


opinion
 

larger

 

flakes

 

factory

 

account

 
suffered
 

peculiar

 

poisoning

 

arsenical

 

acetic


formation

 

assumes

 

yellow

 

continued

 

acquires

 
suffer
 

minutes

 
longer
 

Cupric

 

Roscoe


Schorlemmer

 
understand
 

recommended

 

edition

 

Crookes

 

process

 
edited
 

Technology

 
Wagner
 
Handbook