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hich, being an excellent electrolyte when fluid, was a perfect insulator when solid, namely, borate of lead, in the form of a glass plate, and connecting the sides and the edges of this mass with the metallic plates, sometimes in contact with the poles of a voltaic battery, and sometimes even with the electric machine, for the advantage of the much higher intensity then obtained, I passed a polarized ray across it in various directions, as before, but could not obtain the slightest appearance of action upon the light. Hence I conclude, that notwithstanding the new and extraordinary state which must be assumed by an electrolyte, either during decomposition (when a most enormous quantity of electricity must be traversing it), or in the state of tension which is assumed as preceding decomposition, and which might be supposed to be retained in the solid form of the electrolyte, still it has no power of affecting a polarized ray of light; for no kind of structure or tension can in this way be rendered evident. 956. There is, however, one beautiful experimental proof of a state of tension acquired by the metals and the electrolyte before the electric current is produced, and _before contact_ of the different metals is made (915.); in fact, at that moment when chemical forces only are efficient as a cause of action. I took a voltaic apparatus, consisting of a single pair of large plates, namely, a cylinder of amalgamated zinc, and a double cylinder of copper. These were put into a jar containing dilute sulphuric acid[A], and could at pleasure be placed in metallic communication by a copper wire adjusted so as to dip at the extremities into two cups of mercury connected with the two plates. [A] When nitro-sulphuric acid is used, the spark is more powerful, but local chemical action can then commence, and proceed without requiring metallic contact. 957. Being thus arranged, there was no chemical action whilst the plates were not connected. On _making_ the connexion a spark was obtained[A], and the solution was immediately decomposed. On breaking it, the usual spark was obtained, and the decomposition ceased. In this case it is evident that the first spark must have occurred before metallic contact was made, for it passed through an interval of air; and also that it must have tended to pass before the electrolytic action began; for the latter could not take place until the current passed, and the current could not pass
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