FREE BOOKS

Author's List




PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   >>  
pecially of the varieties of iron and steel. Between these condensed compounds and the pure elements the continuous transition of the physical and chemical properties is often effected by insensible degrees, by a mixture of definite compounds. The following letter appears in a recent number of the _Chemical News_. _Sir_: In a recently published lecture, Mr. Meldola seems to call in question the existence of allotropic silver. This opinion does not appear, however, to be based on any adequate study of the subject, but to be somewhat conjectural in its nature. No experimental support of any sort is given, and the only argument offered (if such it can be called) is that this altered form of silver is analogous to that of metals whose properties have been greatly changed by being _alloyed_ with small quantities of other metals. Does, then, Mr. Meldola suppose that a silver alloy can be formed by precipitating silver in the presence of another metal from an aqueous solution, or that one can argue from alloys, which are solutions, to molecular compounds or lakes? Moreover, he has overlooked the fact that allotropic silver can be obtained in the absence of any metal with which silver is capable of combining, as in the case of its formation by the action of soda and dextrine. Silver cannot be alloyed with sodium. Mr. Meldola cites Prange as having shown that allotropic silver obtained with the aid of ferrous citrate contains traces of iron, a fact which was published by me several years earlier, with an analytical determination of the amount of iron found. Mr. Prange repeated and confirmed this fact of the presence of iron (in this particular case), and my other observations generally, and was fully convinced of the existence of both soluble and insoluble allotropic silver. Mr. Meldola's quotation of Mr. Prange would not convey this impression to the reader. Of the many forms of allotropic silver, two of the best marked are the blue and the yellow. Blue allotropic silver is formed in many reactions with the aid of many wholly different reagents. To suppose that each of these many substances is capable of uniting in minute quantity with silver to produce in all cases an identical result, the same product with identical color and properties, would be an absurdity. Gold-colored allotropic silver in thin films is converted by the slightest pressure to normal silver. A glass rod drawn over it with a gentle pressure le
PREV.   NEXT  
|<   91   92   93   94   95   96   97   98   99   100   101   102   >>  



Top keywords:

silver

 
allotropic
 
Meldola
 

properties

 
Prange
 
compounds
 
alloyed
 

metals

 

pressure

 

identical


capable
 

obtained

 

formed

 

suppose

 
presence
 
existence
 

published

 

generally

 

convinced

 
observations

repeated
 

confirmed

 

convey

 

impression

 
reader
 

Between

 

quotation

 
soluble
 

insoluble

 
amount

analytical
 

sodium

 

dextrine

 

Silver

 

condensed

 
ferrous
 

earlier

 

citrate

 

traces

 
determination

colored

 

converted

 

absurdity

 

product

 
slightest
 

pecially

 

gentle

 
normal
 

result

 

varieties